Triethyl-{(R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methyl-pent-4-enyloxy}-silane

Base Information

Chemical Name:Triethyl-{(R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methyl-pent-4-enyloxy}-silane
CAS No.:713143-75-0
Molecular Formula:C₂₂H₃₈O₃Si
Molecular Weight:378.627
Hs Code.:

Synonyms:Triethyl-{(R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methyl-pent-4-enyloxy}-silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Triethyl-{(R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methyl-pent-4-enyloxy}-silane

Chemical Property:

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Technology Process of Triethyl-{(R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methyl-pent-4-enyloxy}-silane

There total 5 articles about Triethyl-{(R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methyl-pent-4-enyloxy}-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (R)-6-(4-Methoxy-benzyloxy)-2-methyl-4-triethylsilanyloxy-hexanal

: 74-95-3
1,1-dibromomethane

: 713143-75-0
Triethyl-{(R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methyl-pent-4-enyloxy}-silane

Guidance literature:: With titanium tetrachloride; zinc; In dichloromethane; at 20 ℃; for 0.166667h;
DOI:10.1002/anie.200453663

Reference yield:

: 713143-72-7
(S)-1-(4-methoxy-benzyloxy)-5-methyl-hex-5-en-3-ol

: 713143-75-0
Triethyl-{(R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methyl-pent-4-enyloxy}-silane

Guidance literature:: Multi-step reaction with 4 steps

1.1: 97 percent / imidazole; 4-dimethylaminopyridine / CH₂Cl₂ / 0.5 h / 20 °C

2.1: BH₃*THF / tetrahydrofuran / 2 h / 0 °C

2.2: 95 percent / NaOH; H₂O₂ / H₂O / 2 h / 0 °C

3.1: 4-methylmorpholine N-oxide; molecular sieves 4 Angstroem; tetra-n-propylammonium perruthenate / CH₂Cl₂ / 0.5 h / 20 °C

4.1: Zn; TiCl₄ / CH₂Cl₂ / 0.17 h / 20 °C

With 1H-imidazole; dmap; tetrapropylammonium perruthennate; borane-THF; 4 A molecular sieve; titanium tetrachloride; 4-methylmorpholine N-oxide; zinc; In tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.200453663

Reference yield:

: 713143-73-8
(S)-{1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methyl-but-3-enyloxy}-triethylsilane

: 713143-75-0
Triethyl-{(R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methyl-pent-4-enyloxy}-silane

Guidance literature:: Multi-step reaction with 3 steps

1.1: BH₃*THF / tetrahydrofuran / 2 h / 0 °C

1.2: 95 percent / NaOH; H₂O₂ / H₂O / 2 h / 0 °C

2.1: 4-methylmorpholine N-oxide; molecular sieves 4 Angstroem; tetra-n-propylammonium perruthenate / CH₂Cl₂ / 0.5 h / 20 °C

3.1: Zn; TiCl₄ / CH₂Cl₂ / 0.17 h / 20 °C

With tetrapropylammonium perruthennate; borane-THF; 4 A molecular sieve; titanium tetrachloride; 4-methylmorpholine N-oxide; zinc; In tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.200453663