Methyl 2,2,3,3-tetrafluoropropionate

Base Information

• Chemical Name: Methyl 2,2,3,3-tetrafluoropropionate
• CAS No.: 1893-38-5
• Molecular Formula: C4H4 F4 O2
• Molecular Weight: 160.068
• Hs Code.: 2915900090
• European Community (EC) Number: 696-306-2
• DSSTox Substance ID: DTXSID50463267
• Nikkaji Number: J1.568.496H
• Mol file: 1893-38-5.mol

Synonyms:METHYL 2,2,3,3-TETRAFLUOROPROPIONATE;1893-38-5;Methyl 2,2,3,3-tetrafluoropropanoate;MFCD03412257;SCHEMBL898549;C4H4F4O2;DTXSID50463267;AKOS016015315;METHYL2,2,3,3-TETRAFLUOROPROPIONATE;Propanoic acid, 2,2,3,3-tetrafluoro-, methyl ester;Propanoic acid, 2,2,3,3-tetrafluoro-,?methyl ester

Chemical Property of Methyl 2,2,3,3-tetrafluoropropionate

Chemical Property:

• Vapor Pressure: 62.3mmHg at 25°C
• Refractive Index: 1.3195 (589.3 nm 24℃)
• Boiling Point: 93-94℃ (760 Torr)
• Flash Point: 8.1°C
• PSA: 26.30000
• Density: 1.3819 g/cm3 (24℃)
• LogP: 1.05980
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 160.01474201
• Heavy Atom Count: 10
• Complexity: 133

Purity/Quality:

99%, ^*data from raw suppliers

Methyl2,2,3,3-Tetrafluoropropionate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(=O)C(C(F)F)(F)F

Technology Process of Methyl 2,2,3,3-tetrafluoropropionate

There total 5 articles about Methyl 2,2,3,3-tetrafluoropropionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

3,3,4,4,8,8,9,9-octafluoro-5,10-dihydroxy-5,10-dimethoxy-1,6-dioxacyclodecan-2,7-dione (211797-77-2) → methyl 2,2,3,3-tetrafluoropropionate (1893-38-5) + dimethyl tetrafluorosuccinate (356-36-5)

Guidance literature:

at 300 ℃;

Reference yield:

perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) → methyl 2,2,3,3-tetrafluoropropionate (1893-38-5)

Guidance literature:

In methanol;

Reference yield:

3-methoxycarbonyl-2,2,3,3-tetrafluoropropanoic acid (356-33-2) → methyl 2,2,3,3-tetrafluoropropionate (1893-38-5)

Guidance literature:

With sodium methylate; In methanol; acetonitrile; (anodic oxidation);

upstream raw materials:

3-methoxycarbonyl-2,2,3,3-tetrafluoropropanoic acid

diazomethane

2,2,3,3-tetrafluoropropanoic acid

3,3,4,4,8,8,9,9-octafluoro-5,10-dihydroxy-5,10-dimethoxy-1,6-dioxacyclodecan-2,7-dione

Downstream raw materials:

2,5-bis(2,2,3,3-tetrafluoropropionyl)cyclohexane-1,4-dione

2,2,3,3-tetrafluoropropanol

2-Amino-4-(1,1,2,2-tetrafluoroethyl)6-{N-[1-cyclopentyl-2-(3-methylphenoxy)ethyl]amino}-1,3,5-triazine

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