DICHLORO(2-PROPOXY)OXOVANADIUM (V)

Base Information

• Chemical Name: DICHLORO(2-PROPOXY)OXOVANADIUM (V)
• CAS No.: 1636-01-7
• Molecular Formula: C3H7 Cl2 O2 V
• Molecular Weight: 196.935
• Hs Code.: 2914700090
• Mol file: 1636-01-7.mol

Synonyms:Vanadium,dichloroisopropoxyoxo- (7CI,8CI); 2-Propanol, vanadium complex;Dichloro(isopropoxo)oxovanadium; Dichlorooxo(2-propanolato)vanadium

Chemical Property of DICHLORO(2-PROPOXY)OXOVANADIUM (V)

Chemical Property:

• PSA: 26.30000
• LogP: 2.13590

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DICHLORO(2-PROPOXY)OXOVANADIUM (V)

There total 6 articles about DICHLORO(2-PROPOXY)OXOVANADIUM (V) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

9-chloro-9-borabicyclo{3.3.1}nonane (22086-34-6) + vanadyl chloride diisopropoxide (1636-00-6) → vanadyl dichloride isopropoxide (1636-01-7)

Guidance literature:

In chloroform-d1;

DOI:10.1039/d0cc04395h

Reference yield: 85.0%

vanadium(V) oxytriisopropoxide (5588-84-1) + vanadium(V) oxychloride (7727-18-6) → vanadyl dichloride isopropoxide (1636-01-7)

Guidance literature:

In toluene; (N2); standard Schlenk technique; VOCl3 (2 equiv.) added dropwise to VO(Oi-Pr)3 in toluene (1 equiv.); solvent removed in vac.; residue stripped (pentane); flash distd.;

DOI:10.1021/ic991415s

Reference yield:

vanadium(V) oxytriisopropoxide (5588-84-1) → vanadyl dichloride isopropoxide (1636-01-7) + vanadyl chloride diisopropoxide (1636-00-6)

Guidance literature:

With hydrogenchloride; In pentane; pumping HCl through soln. of trialkoxide at ambient temp. for 12 s yielded monochloride; pumping HCl for 30 s yielded dichloride; monitoring by 51V-NMR;

DOI:10.1021/ja00038a015

upstream raw materials:

vanadium(V) oxychloride

isopropyl alcohol

vanadium(V) oxytriisopropoxide

VOCl₂OC(C₆H₅)3

Downstream raw materials:

2-Methyl-5-phenyl-furan-3-carboxylic acid isopropyl ester

2-Methyl-5-phenyl-5-trimethylsilanyl-4,5-dihydro-furan-3-carboxylic acid isopropyl ester

bis(N-phenyl-N-trimethylsilylamino)-isopropoxo-oxovanadium(V)

vanadium(V) oxychloride