vanadyl chloride diisopropoxide

Base Information

• Chemical Name: vanadyl chloride diisopropoxide
• CAS No.: 1636-00-6
• Molecular Formula: C₆H₁₄ClO₃V
• Molecular Weight: 220.57
• Mol file: 1636-00-6.mol

Synonyms:vanadyl chloride diisopropoxide

Chemical Property of vanadyl chloride diisopropoxide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of vanadyl chloride diisopropoxide

There total 3 articles about vanadyl chloride diisopropoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

vanadyl dichloride isopropoxide (1636-01-7) → vanadium(V) oxychloride (7727-18-6) + vanadyl chloride diisopropoxide (1636-00-6)

Guidance literature:

In dichloromethane; dichloromethane-d2; redistribution, -80°C; detn. by (51)-NMR;

Reference yield:

vanadium(V) oxytriisopropoxide (5588-84-1) → vanadyl dichloride isopropoxide (1636-01-7) + vanadyl chloride diisopropoxide (1636-00-6)

Guidance literature:

With hydrogenchloride; In pentane; pumping HCl through soln. of trialkoxide at ambient temp. for 12 s yielded monochloride; pumping HCl for 30 s yielded dichloride; monitoring by 51V-NMR;

DOI:10.1021/ja00038a015

Reference yield:

VOCl2OC(C6H5)3 (134939-14-3) + isopropyl alcohol (67-63-0,8013-70-5) → VO(OCH(CH3)2)(OC(C6H5)3) (134939-05-2) + vanadyl dichloride isopropoxide (1636-01-7) + vanadyl chloride diisopropoxide (1636-00-6)

Guidance literature:

In hexane; byproducts: HCl; warmed to 50°C, 2-propanol added; (51)V-NMR;

upstream raw materials:

vanadium(V) oxytriisopropoxide

vanadyl dichloride isopropoxide

VOCl₂OC(C₆H₅)3

isopropyl alcohol

Downstream raw materials:

bis(diethylamido)(isopropoxy)oxovanadium(V)

vanadium(V) oxytriisopropoxide

vanadyl dichloride isopropoxide