Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-CH3OC6H4CH=CHC6H4OCH3)

Base Information

• Chemical Name: Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-CH3OC6H4CH=CHC6H4OCH3)
• CAS No.: 122395-80-6
• Molecular Formula: C₅₀H₄₄FeO₂P₂Pd
• Molecular Weight: 901.113
• Mol file: 122395-80-6.mol

Synonyms:Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-CH3OC6H4CH=CHC6H4OCH3)

Chemical Property of Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-CH3OC6H4CH=CHC6H4OCH3)

Chemical Property:

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Technology Process of Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-CH3OC6H4CH=CHC6H4OCH3)

There total 5 articles about Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-CH3OC6H4CH=CHC6H4OCH3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1,1`-bis(diphenylphosphino)ferrocene)Pd(p-OMeC6H4CHCH)Br → Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-CH3OC6H4CH=CHC6H4OCH3) (122395-80-6) + Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-CH3OC6H4CH=CHPh) (124268-97-9)

Guidance literature:

With phenylmagnesium bromide; In tetrahydrofuran; Ar-atmosphere; -80°C; not isolated, determined by NMR spectroscopy;

DOI:10.1021/om00116a010

Reference yield:

[1,1'-bis(diphenylphosphino)ferrocene]Pd(η(2)-cyclooctatetraene) (122395-71-5) + 4,2'-dimethoxystilbene (858237-53-3) → Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-CH3OC6H4CH=CHC6H4OCH3) (122395-80-6)

Guidance literature:

In not given; Ar-atmosphere; -30°C;

DOI:10.1021/om00116a010

Reference yield:

(1,1`-bis(diphenylphosphino)ferrocene)Pd(p-OMeC6H4CHCH)Br + 4-flourophenylmagnesium bromide (352-13-6) → Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-CH3OC6H4CH=CHC6H4OCH3) (122395-80-6) + Pd{1,1'-bis(diphenylphosphino)ferrocene}(η2-4-CH3OC6H4CH=CHC6H4-3-F) (124268-95-7)

Guidance literature:

In tetrahydrofuran; Ar-atmosphere; -80°C; not isolated, determined by NMR spectroscopy;

DOI:10.1021/om00116a010

upstream raw materials:

[1,1'-bis(diphenylphosphino)ferrocene]Pd(η(2)-cyclooctatetraene)

4,2'-dimethoxystilbene

4-flourophenylmagnesium bromide

(3-methoxyphenyl)magnesium bromide