[(E)-3-cyclohexylbut-2-enyl] methyl carbonate

Base Information

Chemical Name:[(E)-3-cyclohexylbut-2-enyl] methyl carbonate
CAS No.:155184-90-0
Molecular Formula:C₁₂H₂₀O₃
Molecular Weight:212.289
Hs Code.:
DSSTox Substance ID:DTXSID001245142

Synonyms:155184-90-0;DTXSID001245142;(2E)-3-Cyclohexyl-2-buten-1-yl methyl carbonate

Suppliers and Price of [(E)-3-cyclohexylbut-2-enyl] methyl carbonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [(E)-3-cyclohexylbut-2-enyl] methyl carbonate

Chemical Property:

XLogP3:4.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:212.14124450
Heavy Atom Count:15
Complexity:227

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=CCOC(=O)OC)C1CCCCC1
Isomeric SMILES:C/C(=C\COC(=O)OC)/C1CCCCC1

Technology Process of [(E)-3-cyclohexylbut-2-enyl] methyl carbonate

There total 1 articles about [(E)-3-cyclohexylbut-2-enyl] methyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 79-22-1
methyl chloroformate

: 131719-67-0
(E)-3-cyclohexylbut-2-en-1-ol

: 155184-90-0
(E)-3-cyclohexylbut-2-en-1-yl methyl carbonate

Guidance literature:: With pyridine; In benzene; at 0 ℃; for 1.5h;
DOI:10.1016/S0040-4020(99)01107-2

Reference yield: 98.0%

: 155184-90-0
(E)-3-cyclohexylbut-2-en-1-yl methyl carbonate

: 73183-34-3
bis(pinacol)diborane

: 1238945-31-7
(R)-2-(2-cyclohexylbut-3-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With (C₆H₅)2C₃N₂H₃((CH₃)3C₆H₂)C₆H₄SO₃; sodium methylate; copper(II) bis(trifluoromethanesulfonate); In 1,2-dimethoxyethane; at -30 ℃; for 24h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ja104254d

Reference yield:

: 155184-90-0
(E)-3-cyclohexylbut-2-en-1-yl methyl carbonate

: 125847-56-5
(R)-(but-3-en-2-yl)cyclohexane

: (S)-(but-3-en-2-yl)cyclohexane

Guidance literature:: With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; formic acid; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; (R)-(+)-3-diphenylphosphino-3'-methoxy-4,4'-biphenanthryl; In 1,4-dioxane; at 20 ℃; for 22h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1021/ja00081a051