Stannane, tris(pentafluorophenyl)phenyl-

Base Information

• Chemical Name: Stannane, tris(pentafluorophenyl)phenyl-
• CAS No.: 1262-57-3
• Molecular Formula: C₂₄H₅F₁₅Sn
• Molecular Weight: 696.99
• Mol file: 1262-57-3.mol

Synonyms:Tin,tris(pentafluorophenyl)phenyl- (7CI)

Chemical Property of Stannane, tris(pentafluorophenyl)phenyl-

Chemical Property:

• PSA: 0.00000
• LogP: 5.15050

Purity/Quality:

99% ^*data from raw suppliers

PHENYLTRIS(2,3,4,5,6-PENTAFLUOROPHENYL)TIN Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Stannane, tris(pentafluorophenyl)phenyl-

There total 4 articles about Stannane, tris(pentafluorophenyl)phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

2,3,4,5,6-pentafluorophenylmagnesium bromide (879-05-0) + phenyltin(IV) tribromide (7727-17-5) → (C6F5)3Sn(C6H5) (1262-57-3)

Guidance literature:

In diethyl ether; refluxing, 3 days;;

Reference yield: 83.0%

bromobenzene (108-86-1,52753-63-6) + tris-(pentafluoro phenyl) bromo stannane (2874-94-4) → (C6F5)3Sn(C6H5) (1262-57-3)

Guidance literature:

With magnesium; In diethyl ether; Ar-atmosphere; addn. of slight excess of Grignard reagent (prepd. from Mg and C6H5Br) to Sn-compd. at 0°C, stirring (room temp., 8 h); filtration (celite), chromy. (SiO2, hexane);

DOI:10.1016/S0022-328X(98)00928-0

Reference yield: 72.0%

2,3,4,5,6-pentafluorophenylmagnesium bromide (879-05-0) + phenyltin trichloride (1124-19-2) → (C6F5)3Sn(C6H5) (1262-57-3)

Guidance literature:

In diethyl ether; refluxing;;

upstream raw materials:

phenyltin trichloride

pentafluorophenylmagnesium chloride

bromobenzene

tris-(pentafluoro phenyl) bromo stannane