Cinnamaldehyde 2,4-dinitrophenylhydrazone

Base Information

• Chemical Name: Cinnamaldehyde 2,4-dinitrophenylhydrazone
• CAS No.: 1237-69-0
• Molecular Formula: C15H12 N4 O4
• Molecular Weight: 312.285
• Hs Code.: 2928000090
• DSSTox Substance ID: DTXSID80924573
• Mol file: 1237-69-0.mol

Synonyms:Cinnamaldehyde 2,4-dinitrophenylhydrazone;1237-69-0;N-(cinnamylideneamino)-2,4-dinitroaniline;DTXSID80924573;1-(2,4-dinitrophenyl)-2-(3-phenylprop-2-en-1-ylidene)hydrazine

Chemical Property of Cinnamaldehyde 2,4-dinitrophenylhydrazone

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.626
• Boiling Point: 503.3°Cat760mmHg
• Flash Point: 258.2°C
• PSA: 116.03000
• Density: 1.31g/cm³
• LogP: 4.73350
• XLogP3: 2.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 4
• Exact Mass: 312.08585488
• Heavy Atom Count: 23
• Complexity: 463

Purity/Quality:

98%Min ^*data from raw suppliers

CINNAMALDEHYDE (2,4-DINITROPHENYL)HYDRAZONE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C=CC=NNC2=C(C=C(C=C2)[N+](=O)[O-])[N+](=O)[O-]

Technology Process of Cinnamaldehyde 2,4-dinitrophenylhydrazone

There total 9 articles about Cinnamaldehyde 2,4-dinitrophenylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

3-phenyl-propenal (104-55-2) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → cinnamaldehyde 2,4-dinitrophenylhydrazone (1237-69-0)

Guidance literature:

With oxidized single-walled carbon nanotubes(SWCNs-COOH); In ethanol; at 80 ℃; for 0.75h;

Reference yield: 92.28%

3-Phenylpropenol (104-54-1) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → cinnamaldehyde 2,4-dinitrophenylhydrazone (1237-69-0)

Guidance literature:

3-Phenylpropenol; With C₉₃H₇₃Br₄N₃O₂P₄Ru₂; oxygen; In dichloromethane; at 20 ℃; for 6h; under 760.051 Torr;

(2,4-dinitro-phenyl)-hydrazine;

DOI:10.3109/10799890903555616

Reference yield: 70.0%

cinnamaldoxime (13372-81-1) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → cinnamaldehyde 2,4-dinitrophenylhydrazone (1237-69-0)

Guidance literature:

iron(III) perchlorate; In 1,2-dichloro-ethane; at 20 ℃; for 32h;

DOI:10.1016/j.mencom.2007.05.021

upstream raw materials:

3-phenyl-propenal

(2,4-dinitro-phenyl)-hydrazine

(E)-3-phenylpropenal

(2E)-3-phenyl-2-propen-1-ol

Downstream raw materials:

C₁₅H₁₁ClN₄O₄

Refernces

• 1、 Madaselvi,Padma Priya,Jeyaraj,Arun Paul,Kalaivani,Shahul Meeran,Arunachalam. "Synthesis, spectral investigation of Ni(II) schiff base complexes: Antimicrobial activities and catalytic oxidation of alcohols". . p. 1682 - 1686. Retrieved 2016/07/06.
• 2、 Zhu, Chenjie,Yoshimura, Akira,Wei, Yunyang,Nemykin, Victor N.,Zhdankin, Viktor V.. "Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent: A convenient recyclable reagent for catalytic oxidation". supporting information; experimental part. p. 1438 - 1444. Retrieved 2012/04/04.