1-<4-(2-t-butyldimethylsilyloxyethoxy)phenyl>-1,2-diphenyl-2-iodoethylene

Base Information

Chemical Name:1-<4-(2-t-butyldimethylsilyloxyethoxy)phenyl>-1,2-diphenyl-2-iodoethylene
CAS No.:113202-57-6
Molecular Formula:C₂₈H₃₃IO₂Si
Molecular Weight:556.559
Hs Code.:

Synonyms:1-<4-(2-t-butyldimethylsilyloxyethoxy)phenyl>-1,2-diphenyl-2-iodoethylene

Suppliers and Price of 1-<4-(2-t-butyldimethylsilyloxyethoxy)phenyl>-1,2-diphenyl-2-iodoethylene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-<4-(2-t-butyldimethylsilyloxyethoxy)phenyl>-1,2-diphenyl-2-iodoethylene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-<4-(2-t-butyldimethylsilyloxyethoxy)phenyl>-1,2-diphenyl-2-iodoethylene

There total 8 articles about 1-<4-(2-t-butyldimethylsilyloxyethoxy)phenyl>-1,2-diphenyl-2-iodoethylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 113202-53-2
4-(2-t-butyldimethylsilyloxyethoxy)phenyl-1,2-diphenyl-2-trimethylstannylethylene

: 113202-57-6
1-<4-(2-t-butyldimethylsilyloxyethoxy)phenyl>-1,2-diphenyl-2-iodoethylene

Guidance literature:: With iodine; In tetrahydrofuran; dichloromethane; for 0.0833333h;
DOI:10.1016/0039-128X(86)90017-6

Reference yield: 54.0%

: 113202-52-1
2-bromo-1-<4-(2-t-butyldimethylsilyloxyethoxy)phenyl>-1,2-diphenylethylene

: 113202-57-6
1-<4-(2-t-butyldimethylsilyloxyethoxy)phenyl>-1,2-diphenyl-2-iodoethylene

Guidance literature:: With N-iodo-succinimide; tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 ℃; for 0.333333h;
DOI:10.1016/0039-128X(86)90017-6

Reference yield:

: 451-40-1
phenyl benzyl ketone

: 113202-57-6
1-<4-(2-t-butyldimethylsilyloxyethoxy)phenyl>-1,2-diphenyl-2-iodoethylene

Guidance literature:: Multi-step reaction with 4 steps

2: 95 percent / imidazole / dimethylformamide / 0.08 h

3: 72 percent / Br₂ / CH₂Cl₂ / 0.17 h

4: 54 percent / tBuLi, NIS / tetrahydrofuran; pentane / 0.33 h / -78 °C

With 1H-imidazole; N-iodo-succinimide; bromine; tert.-butyl lithium; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; pentane;
DOI:10.1016/0039-128X(86)90017-6