C₅₁H₆₀O₅SSi₂

Base Information

Chemical Name:C₅₁H₆₀O₅SSi₂
CAS No.:943003-71-2
Molecular Formula:C₅₁H₆₀O₅SSi₂
Molecular Weight:841.271
Hs Code.:

C<sub>51</sub>H<sub>60</sub>O<sub>5</sub>SSi<sub>2</sub>

Synonyms:C₅₁H₆₀O₅SSi₂

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₅₁H₆₀O₅SSi₂

Chemical Property:

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Technology Process of C₅₁H₆₀O₅SSi₂

There total 8 articles about C₅₁H₆₀O₅SSi₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 629615-43-6
(1S,2S,3S,4aR,6S,7R,8aS)-2,3-bis(tert-butyldiphenylsilyloxymethyl)-6,7-epoxydecalin-1-ol

: 1005-56-7
phenylcarbonochloridothioate

: 943003-71-2
C₅₁H₆₀O₅SSi₂

Guidance literature:: (1S,2S,3S,4aR,6S,7R,8aS)-2,3-bis(tert-butyldiphenylsilyloxymethyl)-6,7-epoxydecalin-1-ol; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.166667h;

phenylcarbonochloridothioate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 12h; Further stages.;
DOI:10.1002/ejoc.200700068

Reference yield:

: C₂₈H₄₆O₄

: 943003-71-2
C₅₁H₆₀O₅SSi₂

Guidance literature:: Multi-step reaction with 8 steps

1.1: 99 percent / LiAlH₄ / tetrahydrofuran / 2 h / Heating

2.1: 99 percent / imidazole / CH₂Cl₂ / 12 h / 0 - 20 °C

3.1: 54 percent / SeO₂ / dioxane; H₂O / 36 h / 90 °C

4.1: 86 percent / MnO₂ / CH₂Cl₂ / 9 h / Heating

5.1: 95 percent / AlCl₃; Me₃Al / toluene / 36 h / 20 °C

6.1: 87 percent / NaBH₄ / CH₂Cl₂; methanol / 16 h / 0 - 20 °C

7.1: 81 percent / mCPBA / CH₂Cl₂ / 2.5 h / -30 - 0 °C

8.1: nBuLi / tetrahydrofuran; hexane / 0.17 h / -78 °C

8.2: 96 percent / tetrahydrofuran; hexane / 12 h / -78 - 20 °C

With 1H-imidazole; manganese(IV) oxide; sodium tetrahydroborate; lithium aluminium tetrahydride; n-butyllithium; aluminium trichloride; selenium(IV) oxide; trimethylaluminum; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; 1,4-dioxane; methanol; hexane; dichloromethane; water; toluene; 5.1: Diels-Alder reaction;
DOI:10.1002/ejoc.200700068

Reference yield:

: 943003-66-5
(2S,3S,4aS,8aS)-2,3-bis(tert-butyldiphenylsilyloxymethyl)-3,4,4a,5,8,8a-hexahydro-2H-naphthalen-1-one

: 943003-71-2
C₅₁H₆₀O₅SSi₂

Guidance literature:: Multi-step reaction with 3 steps

1.1: 87 percent / NaBH₄ / CH₂Cl₂; methanol / 16 h / 0 - 20 °C

2.1: 81 percent / mCPBA / CH₂Cl₂ / 2.5 h / -30 - 0 °C

3.1: nBuLi / tetrahydrofuran; hexane / 0.17 h / -78 °C

3.2: 96 percent / tetrahydrofuran; hexane / 12 h / -78 - 20 °C

With sodium tetrahydroborate; n-butyllithium; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; hexane; dichloromethane;
DOI:10.1002/ejoc.200700068