ethyl <2,3-dichloro-4-<<3-(hydroxymethyl)-4-(benzyloxy)phenoxy>methyl>phenoxy>acetate

Base Information

Chemical Name:ethyl <2,3-dichloro-4-<<3-(hydroxymethyl)-4-(benzyloxy)phenoxy>methyl>phenoxy>acetate
CAS No.:93134-97-5
Molecular Formula:C₂₅H₂₄Cl₂O₆
Molecular Weight:491.368
Hs Code.:

Synonyms:ethyl <2,3-dichloro-4-<<3-(hydroxymethyl)-4-(benzyloxy)phenoxy>methyl>phenoxy>acetate

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Chemical Property of ethyl <2,3-dichloro-4-<<3-(hydroxymethyl)-4-(benzyloxy)phenoxy>methyl>phenoxy>acetate

Chemical Property:

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Technology Process of ethyl <2,3-dichloro-4-<<3-(hydroxymethyl)-4-(benzyloxy)phenoxy>methyl>phenoxy>acetate

There total 7 articles about ethyl <2,3-dichloro-4-<<3-(hydroxymethyl)-4-(benzyloxy)phenoxy>methyl>phenoxy>acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 100-39-0
benzyl bromide

: 93135-33-2
ethyl <2,3-dichloro-4-<<4-hydroxy-3-(hydroxymethyl)phenoxy>methyl>phenoxy>acetate

: 93134-97-5
ethyl <2,3-dichloro-4-<<3-(hydroxymethyl)-4-(benzyloxy)phenoxy>methyl>phenoxy>acetate

Guidance literature:: With potassium carbonate; In acetone; for 4h; Heating;
DOI:10.1021/jm00379a016

Reference yield:

: 16861-23-7
ethyl <2,3-dichloro-4-formylphenoxy> acetate

: 93134-97-5
ethyl <2,3-dichloro-4-<<3-(hydroxymethyl)-4-(benzyloxy)phenoxy>methyl>phenoxy>acetate

Guidance literature:: Multi-step reaction with 5 steps

1: 94 percent / NaBH₄ / ethanol / 0.25 h / 5 °C

2: 100 percent / SOCl₂ / CHCl₃ / 1 h

3: 60 percent / K₂CO₃ / dimethylformamide / 6 h / 65 °C

4: 65percent aq. AcOH / tetrahydrofuran / 3 h / 50 °C

5: 59 percent / K₂CO₃ / acetone / 4 h / Heating

With sodium tetrahydroborate; thionyl chloride; potassium carbonate; acetic acid; In tetrahydrofuran; ethanol; chloroform; N,N-dimethyl-formamide; acetone;
DOI:10.1021/jm00379a016

Reference yield:

: 495-08-9
gentisyl alcohol

: 93134-97-5
ethyl <2,3-dichloro-4-<<3-(hydroxymethyl)-4-(benzyloxy)phenoxy>methyl>phenoxy>acetate

Guidance literature:: Multi-step reaction with 4 steps

1: 71 percent / p-TsOH / dimethylformamide / Ambient temperature; overnight

2: 60 percent / K₂CO₃ / dimethylformamide / 6 h / 65 °C

3: 65percent aq. AcOH / tetrahydrofuran / 3 h / 50 °C

4: 59 percent / K₂CO₃ / acetone / 4 h / Heating

With potassium carbonate; toluene-4-sulfonic acid; acetic acid; In tetrahydrofuran; N,N-dimethyl-formamide; acetone;
DOI:10.1021/jm00379a016