[Pd{κ²C,O-C(C₆H₄ⁿBu-4)=C(C₆H₄ⁿBu-4)C₆H₄(CH₂)₂C(O)NH₂-2}I(N,N,N′,N′-tetramethylethylenediamine)](triflate)

Base Information

• Chemical Name: [Pd{κ²C,O-C(C₆H₄ⁿBu-4)=C(C₆H₄ⁿBu-4)C₆H₄(CH₂)₂C(O)NH₂-2}I(N,N,N′,N′-tetramethylethylenediamine)](triflate)
• CAS No.: 1423780-94-2
• Molecular Formula: CF₃O₃S*C₃₇H₅₂N₃OPd
• Molecular Weight: 810.33

Synonyms:[Pd{κ²C,O-C(C₆H₄ⁿBu-4)=C(C₆H₄ⁿBu-4)C₆H₄(CH₂)₂C(O)NH₂-2}I(N,N,N′,N′-tetramethylethylenediamine)](triflate)

Chemical Property of [Pd{κ²C,O-C(C₆H₄ⁿBu-4)=C(C₆H₄ⁿBu-4)C₆H₄(CH₂)₂C(O)NH₂-2}I(N,N,N′,N′-tetramethylethylenediamine)](triflate)

Chemical Property:

Purity/Quality:

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Technology Process of [Pd{κ²C,O-C(C₆H₄ⁿBu-4)=C(C₆H₄ⁿBu-4)C₆H₄(CH₂)₂C(O)NH₂-2}I(N,N,N′,N′-tetramethylethylenediamine)](triflate)

There total 6 articles about [Pd{κ²C,O-C(C₆H₄ⁿBu-4)=C(C₆H₄ⁿBu-4)C₆H₄(CH₂)₂C(O)NH₂-2}I(N,N,N′,N′-tetramethylethylenediamine)](triflate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

[Pd{κ2C,O-C6H4(CH2)2C(O)NH2-2}I(N,N,N′,N′-tetramethylethylenediamine)](triflate) (1423780-79-3) + 1,2-bis(4-butylphenyl)ethyne (80221-11-0) → [Pd{κ2C,O-C(C6H4nBu-4)=C(C6H4nBu-4)C6H4(CH2)2C(O)NH2-2}I(N,N,N′,N′-tetramethylethylenediamine)](triflate) (1423780-94-2)

Guidance literature:

In dichloromethane; at 20 ℃; for 3h;

DOI:10.1021/om4000192

Reference yield:

3-(2-bromophenyl)propanamide (55223-26-2) → [Pd{κ2C,O-C(C6H4nBu-4)=C(C6H4nBu-4)C6H4(CH2)2C(O)NH2-2}I(N,N,N′,N′-tetramethylethylenediamine)](triflate) (1423780-94-2)

Guidance literature:

Multi-step reaction with 4 steps

1: copper(l) iodide; sodium iodide; trans-N,N'-dimethylcyclohexane-1,2-diamine / 1,4-dioxane / 72 h / 140 °C / Inert atmosphere

2: dichloromethane / 1 h / 20 °C / Inert atmosphere

3: acetone / 0.5 h

4: dichloromethane / 3 h / 20 °C

With copper(l) iodide; trans-N,N'-dimethylcyclohexane-1,2-diamine; sodium iodide; In 1,4-dioxane; dichloromethane; acetone;

DOI:10.1021/om4000192

Reference yield:

3-(2-bromophenyl)propanoyl chloride (90725-40-9) → [Pd{κ2C,O-C(C6H4nBu-4)=C(C6H4nBu-4)C6H4(CH2)2C(O)NH2-2}I(N,N,N′,N′-tetramethylethylenediamine)](triflate) (1423780-94-2)

Guidance literature:

Multi-step reaction with 5 steps

1: ammonia / ethyl acetate; water / 1 h / 0 °C

2: copper(l) iodide; sodium iodide; trans-N,N'-dimethylcyclohexane-1,2-diamine / 1,4-dioxane / 72 h / 140 °C / Inert atmosphere

3: dichloromethane / 1 h / 20 °C / Inert atmosphere

4: acetone / 0.5 h

5: dichloromethane / 3 h / 20 °C

With copper(l) iodide; ammonia; trans-N,N'-dimethylcyclohexane-1,2-diamine; sodium iodide; In 1,4-dioxane; dichloromethane; water; ethyl acetate; acetone;

DOI:10.1021/om4000192

upstream raw materials:

3-(2-iodophenyl)propanamide

[Pd{C₆H₄(CH₂)₂C(O)NH₂-2}I(N,N,N′,N′-tetramethylethylenediamine)]

[Pd{κ²C,O-C₆H₄(CH₂)₂C(O)NH₂-2}I(N,N,N′,N′-tetramethylethylenediamine)](triflate)

1,2-bis(4-butylphenyl)ethyne

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