Phenyl 2-azido-2-deoxy-3,4-O-isopropylidene-6-O-(tert-butyldimethylsilyl)-1-seleno-α-D-galactopyranoside

Base Information

Chemical Name:Phenyl 2-azido-2-deoxy-3,4-O-isopropylidene-6-O-(tert-butyldimethylsilyl)-1-seleno-α-D-galactopyranoside
CAS No.:161822-68-0
Molecular Formula:C₂₁H₃₃N₃O₄SeSi
Molecular Weight:498.556
Hs Code.:

Synonyms:Phenyl 2-azido-2-deoxy-3,4-O-isopropylidene-6-O-(tert-butyldimethylsilyl)-1-seleno-α-D-galactopyranoside

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Chemical Property of Phenyl 2-azido-2-deoxy-3,4-O-isopropylidene-6-O-(tert-butyldimethylsilyl)-1-seleno-α-D-galactopyranoside

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Technology Process of Phenyl 2-azido-2-deoxy-3,4-O-isopropylidene-6-O-(tert-butyldimethylsilyl)-1-seleno-α-D-galactopyranoside

There total 3 articles about Phenyl 2-azido-2-deoxy-3,4-O-isopropylidene-6-O-(tert-butyldimethylsilyl)-1-seleno-α-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 71098-88-9
N-phenylselanylphthalimide

: 161822-65-7
1,5-Anhydro-2-deoxy-3,4-O-isopropylidene-6-O-(tert-butyldimethylsilyl)-D-lyxo-hex-1-enitol

: 161822-68-0
Phenyl 2-azido-2-deoxy-3,4-O-isopropylidene-6-O-(tert-butyldimethylsilyl)-1-seleno-α-D-galactopyranoside

Guidance literature:: With trimethylsilylazide; tetrabutyl ammonium fluoride; In dichloromethane; for 48h; Ambient temperature;
DOI:10.1139/v95-046

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 161822-68-0
Phenyl 2-azido-2-deoxy-3,4-O-isopropylidene-6-O-(tert-butyldimethylsilyl)-1-seleno-α-D-galactopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / imidazole / dimethylformamide / 48 h / 46 °C

2: 66 percent / azidotrimethylsilane, tetra-n-butylammonium fluoride / CH₂Cl₂ / 48 h / Ambient temperature

With 1H-imidazole; trimethylsilylazide; tetrabutyl ammonium fluoride; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1139/v95-046

Reference yield:

: 124477-12-9
2,6-anhydro-5-deoxy-3,4-O-isopropylidene-D-arabino-hex-5-enitol

: 161822-68-0
Phenyl 2-azido-2-deoxy-3,4-O-isopropylidene-6-O-(tert-butyldimethylsilyl)-1-seleno-α-D-galactopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / imidazole / dimethylformamide / 48 h / 46 °C

2: 66 percent / azidotrimethylsilane, tetra-n-butylammonium fluoride / CH₂Cl₂ / 48 h / Ambient temperature

With 1H-imidazole; trimethylsilylazide; tetrabutyl ammonium fluoride; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1139/v95-046