methyl (phenyl 2,3-di-O-benzoyl-4-[4,6-O-di-tert-butylsilylidene-3-O-levulinoyl-2-N-trichloroacetamido-β-D-glucopyranosyl]-1-thio-β-D-glucopyranosyl uronate)

Base Information

Chemical Name:methyl (phenyl 2,3-di-O-benzoyl-4-[4,6-O-di-tert-butylsilylidene-3-O-levulinoyl-2-N-trichloroacetamido-β-D-glucopyranosyl]-1-thio-β-D-glucopyranosyl uronate)
CAS No.:1158797-00-2
Molecular Formula:C₄₈H₅₆Cl₃NO₁₅SSi
Molecular Weight:1053.48
Hs Code.:

methyl (phenyl 2,3-di-O-benzoyl-4-[4,6-O-di-tert-butylsilylidene-3-O-levulinoyl-2-N-trichloroacetamido-β-D-glucopyranosyl]-1-thio-β-D-glucopyranosyl uronate)

Synonyms:methyl (phenyl 2,3-di-O-benzoyl-4-[4,6-O-di-tert-butylsilylidene-3-O-levulinoyl-2-N-trichloroacetamido-β-D-glucopyranosyl]-1-thio-β-D-glucopyranosyl uronate)

Suppliers and Price of methyl (phenyl 2,3-di-O-benzoyl-4-[4,6-O-di-tert-butylsilylidene-3-O-levulinoyl-2-N-trichloroacetamido-β-D-glucopyranosyl]-1-thio-β-D-glucopyranosyl uronate)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl (phenyl 2,3-di-O-benzoyl-4-[4,6-O-di-tert-butylsilylidene-3-O-levulinoyl-2-N-trichloroacetamido-β-D-glucopyranosyl]-1-thio-β-D-glucopyranosyl uronate)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl (phenyl 2,3-di-O-benzoyl-4-[4,6-O-di-tert-butylsilylidene-3-O-levulinoyl-2-N-trichloroacetamido-β-D-glucopyranosyl]-1-thio-β-D-glucopyranosyl uronate)

There total 8 articles about methyl (phenyl 2,3-di-O-benzoyl-4-[4,6-O-di-tert-butylsilylidene-3-O-levulinoyl-2-N-trichloroacetamido-β-D-glucopyranosyl]-1-thio-β-D-glucopyranosyl uronate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1154463-83-8
4,6-O-di-tert-butylsilylidene-3-O-levulinoyl-1-O-(N-phenyltrifluoroacetimidoyl)-2-N-trichloroacetamido-α/β-D-glucopyranoside

: 725228-76-2
methyl (phenyl 2,3-di-O-benzoyl-1-thio-β-D-glucopyranosid)uronate

: 1158797-00-2
methyl (phenyl 2,3-di-O-benzoyl-4-[4,6-O-di-tert-butylsilylidene-3-O-levulinoyl-2-N-trichloroacetamido-β-D-glucopyranosyl]-1-thio-β-D-glucopyranosyl uronate)

Guidance literature:: With trifluorormethanesulfonic acid; In dichloromethane; at 0 ℃; Molecular sieve;
DOI:10.1021/jo9003713

Reference yield: 70.0%

: 1158796-90-7
phenyl 4,6-O-di(tert-butyl)silylidene-1,2-dideoxy-3-O-levulinoyl-2-trichloroacetamido-1-thio-β-D-glucopyranoside

: 725228-76-2
methyl (phenyl 2,3-di-O-benzoyl-1-thio-β-D-glucopyranosid)uronate

: 1158797-00-2
methyl (phenyl 2,3-di-O-benzoyl-4-[4,6-O-di-tert-butylsilylidene-3-O-levulinoyl-2-N-trichloroacetamido-β-D-glucopyranosyl]-1-thio-β-D-glucopyranosyl uronate)

Guidance literature:: phenyl 4,6-O-di(tert-butyl)silylidene-1,2-dideoxy-3-O-levulinoyl-2-trichloroacetamido-1-thio-β-D-glucopyranoside; With trifluoromethylsulfonic anhydride; 1,1'-sulfinylbisbenzene; In dichloromethane; at -60 ℃; for 0.25h; Molecular sieve;

methyl (phenyl 2,3-di-O-benzoyl-1-thio-β-D-glucopyranosid)uronate; In dichloromethane; at -60 - 0 ℃;
DOI:10.1021/jo9003713

Reference yield: 63.0%

: 4,6-O-di(tert-butyl)silylidene-2-deoxy-3-O-levulinoyl-2-trichloroacetamido-D-glucopyranose

: 725228-76-2
methyl (phenyl 2,3-di-O-benzoyl-1-thio-β-D-glucopyranosid)uronate

: 1158797-00-2
methyl (phenyl 2,3-di-O-benzoyl-4-[4,6-O-di-tert-butylsilylidene-3-O-levulinoyl-2-N-trichloroacetamido-β-D-glucopyranosyl]-1-thio-β-D-glucopyranosyl uronate)

Guidance literature:: 4,6-O-di(tert-butyl)silylidene-2-deoxy-3-O-levulinoyl-2-trichloroacetamido-D-glucopyranose; With trifluoromethylsulfonic anhydride; 1,1'-sulfinylbisbenzene; In dichloromethane; at -60 - -40 ℃; for 1h; Molecular sieve;

methyl (phenyl 2,3-di-O-benzoyl-1-thio-β-D-glucopyranosid)uronate; In dichloromethane; at -40 - 0 ℃;
DOI:10.1021/jo9003713