beta-D-Manp-(1->4)-beta-D-Manp-(1->4)-beta-D-Manp

Base Information

• Chemical Name: beta-D-Manp-(1->4)-beta-D-Manp-(1->4)-beta-D-Manp
• CAS No.: 94799-74-3
• Molecular Formula: C₁₈H₃₂O₁₆
• Molecular Weight: 504.442
• DSSTox Substance ID: DTXSID901152023
• Nikkaji Number: J2.295.992A
• Wikidata: Q27132182
• Metabolomics Workbench ID: 62425
• Mol file: 94799-74-3.mol

Synonyms:beta-D-Manp-(1->4)-beta-D-Manp-(1->4)-beta-D-Manp;beta-D-Man-(1->4)-beta-D-Man-(1->4)-beta-D-Man;beta-D-mannosyl-(1->4)-beta-D-mannosyl-(1->4)-beta-D-mannose;beta-D-mannopyranosyl-(1->4)-beta-D-mannopyranosyl-(1->4)-beta-D-mannopyranose;CHEBI:62795;DTXSID901152023;Q27132182;4-O-[4-O-(beta-D-Mannopyranosyl)-beta-D-mannopyranosyl]-beta-D-mannopyranose;O-beta-D-Mannopyranosyl-(1-->4)-O-beta-D-mannopyranosyl-(1-->4)-beta-D-mannopyranose;94799-74-3

Chemical Property of beta-D-Manp-(1->4)-beta-D-Manp-(1->4)-beta-D-Manp

Chemical Property:

• XLogP3: -6.9
• Hydrogen Bond Donor Count: 11
• Hydrogen Bond Acceptor Count: 16
• Rotatable Bond Count: 7
• Exact Mass: 504.16903493
• Heavy Atom Count: 34
• Complexity: 641

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(C1C(C(C(C(O1)OC2C(OC(C(C2O)O)OC3C(OC(C(C3O)O)O)CO)CO)O)O)O)O
• Isomeric SMILES: C([C@@H]1[C@H]([C@@H]([C@@H]([C@@H](O1)O[C@@H]2[C@H](O[C@H]([C@H]([C@H]2O)O)O[C@@H]3[C@H](O[C@H]([C@H]([C@H]3O)O)O)CO)CO)O)O)O)O

Technology Process of beta-D-Manp-(1->4)-beta-D-Manp-(1->4)-beta-D-Manp

There total 51 articles about beta-D-Manp-(1->4)-beta-D-Manp-(1->4)-beta-D-Manp which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

konjac glucomannan → O-β-D-Glucopyranosyl-(1->4)-O-β-D-mannopyranosyl-(1->4)-D-mannopyranose (6401-81-6,17659-52-8,19141-16-3,20702-55-0,52485-13-9,69429-19-2,80446-86-2,80446-87-3,94799-30-1,94799-74-3,113158-51-3,118396-93-3,121153-20-6,133267-59-1,142185-35-1) + D-glucose (50-99-7) + C24H42O21

Guidance literature:

konjac glucomannan; With trichoderma reesei mannanase; In aq. acetate buffer; at 45 ℃; for 48h; pH=5; Enzymatic reaction;

With Aspergillus niger β-glucosidase; In aq. acetate buffer;

DOI:10.1016/j.carres.2013.02.012

Reference yield:

Maltotetraose (1263-76-9,13086-23-2,20702-56-1,69429-16-9,133574-70-6) → maltotriose (6401-81-6,17659-52-8,19141-16-3,20702-55-0,52485-13-9,69429-19-2,80446-86-2,80446-87-3,94799-30-1,94799-74-3,113158-51-3,118396-93-3,121153-20-6,133267-59-1,142185-35-1) + alpha-D-glucopyranose (492-62-6)

Guidance literature:

With phosphate buffer; porcine-pancreatic alpha-amylase; at 25 ℃;

DOI:10.1016/0008-6215(87)80045-9

Reference yield:

Maltotetraose (1263-76-9,13086-23-2,20702-56-1,69429-16-9,133574-70-6) → maltotriose (6401-81-6,17659-52-8,19141-16-3,20702-55-0,52485-13-9,69429-19-2,80446-86-2,80446-87-3,94799-30-1,94799-74-3,113158-51-3,118396-93-3,121153-20-6,133267-59-1,142185-35-1) + D-glucose (50-99-7) + Maltoheptose (1980-14-9,69460-25-9,137767-17-0)

Guidance literature:

With glucan 1,4-α-maltotriohydrolase from Microbacterium imperiale; In aq. phosphate buffer; at 50 ℃; pH=6.5; Enzymatic reaction;

DOI:10.1016/j.carres.2013.11.014

upstream raw materials:

Maltotetraose

2-chloro-4-nitrophenol-α-D-maltotrioside

O-β-D-mannopyranosyl-(1-4)-O-β-D-mannopyranosyl-(1-4)-O-β-D-mannopyranosyl-(1-4)-D-mannopyranose

p-nitrophenyl β-D-cellobioside

Downstream raw materials:

α-D-glucopyranosyl-(1->4)-α-D-glucopyranosyl-(1->4)-D-glucitol

5-O-α-D-glucopyranosyl-(+)-catechin

(+)-catechin 7-α-O-glucoside

D-glucose