[5-(4-tert-butyl-phenyl)-3-dibromomethylene-penta-1,4-diynyl]-trimethyl-silane

Base Information

Chemical Name:[5-(4-tert-butyl-phenyl)-3-dibromomethylene-penta-1,4-diynyl]-trimethyl-silane
CAS No.:879560-01-7
Molecular Formula:C₁₉H₂₂Br₂Si
Molecular Weight:438.277
Hs Code.:

[5-(4-<i>tert</i>-butyl-phenyl)-3-dibromomethylene-penta-1,4-diynyl]-trimethyl-silane

Synonyms:[5-(4-tert-butyl-phenyl)-3-dibromomethylene-penta-1,4-diynyl]-trimethyl-silane

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Chemical Property of [5-(4-tert-butyl-phenyl)-3-dibromomethylene-penta-1,4-diynyl]-trimethyl-silane

Chemical Property:

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Technology Process of [5-(4-tert-butyl-phenyl)-3-dibromomethylene-penta-1,4-diynyl]-trimethyl-silane

There total 3 articles about [5-(4-tert-butyl-phenyl)-3-dibromomethylene-penta-1,4-diynyl]-trimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 879559-99-6
1-(4-tert-butyl-phenyl)-5-trimethylsilanyl-penta-1,4-diyn-3-one

: 558-13-4
carbon tetrabromide

: 879560-01-7
[5-(4-tert-butyl-phenyl)-3-dibromomethylene-penta-1,4-diynyl]-trimethyl-silane

Guidance literature:: With triphenylphosphine; In dichloromethane; at 20 ℃; for 0.5h;
DOI:10.1021/ol0528888

Reference yield:

: 220006-53-1
3-(4-(tert-butyl)phenyl)propiolic acid

: 879560-01-7
[5-(4-tert-butyl-phenyl)-3-dibromomethylene-penta-1,4-diynyl]-trimethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: thionyl chloride / 20 °C

2: AlCl₃ / CH₂Cl₂ / -30 - 20 °C

3: 0.76 g / PPh₃ / CH₂Cl₂ / 0.5 h / 20 °C

With aluminium trichloride; thionyl chloride; triphenylphosphine; In dichloromethane;
DOI:10.1021/ol0528888

Reference yield:

: 220006-54-2
3-<4-(tert-butyl)phenyl>prop-2-ynoyl chloride

: 879560-01-7
[5-(4-tert-butyl-phenyl)-3-dibromomethylene-penta-1,4-diynyl]-trimethyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: AlCl₃ / CH₂Cl₂ / -30 - 20 °C

2: 0.76 g / PPh₃ / CH₂Cl₂ / 0.5 h / 20 °C

With aluminium trichloride; triphenylphosphine; In dichloromethane;
DOI:10.1021/ol0528888