(1R,2S,5S)-2-methyl-4-oxo-5-(2-methyloxiran-2-yl)-4-oxo-2-vinylcyclohexyl pivalate

Base Information

Chemical Name:(1R,2S,5S)-2-methyl-4-oxo-5-(2-methyloxiran-2-yl)-4-oxo-2-vinylcyclohexyl pivalate
CAS No.:1416545-98-6
Molecular Formula:C₁₇H₂₆O₄
Molecular Weight:294.391
Hs Code.:

Synonyms:(1R,2S,5S)-2-methyl-4-oxo-5-(2-methyloxiran-2-yl)-4-oxo-2-vinylcyclohexyl pivalate

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Chemical Property of (1R,2S,5S)-2-methyl-4-oxo-5-(2-methyloxiran-2-yl)-4-oxo-2-vinylcyclohexyl pivalate

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Technology Process of (1R,2S,5S)-2-methyl-4-oxo-5-(2-methyloxiran-2-yl)-4-oxo-2-vinylcyclohexyl pivalate

There total 5 articles about (1R,2S,5S)-2-methyl-4-oxo-5-(2-methyloxiran-2-yl)-4-oxo-2-vinylcyclohexyl pivalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 1416545-96-4
(1R,2S,5S)-2-methyl-4-oxo-5-(prop-1-en-2-yl)-2-vinylcyclohexyl pivalate

: 1416545-98-6
(1R,2S,5S)-2-methyl-4-oxo-5-(2-methyloxiran-2-yl)-4-oxo-2-vinylcyclohexyl pivalate

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1021/ol3031999

Reference yield:

: 1416545-94-2
C₁₅H₂₂O₃

: 1416545-98-6
(1R,2S,5S)-2-methyl-4-oxo-5-(2-methyloxiran-2-yl)-4-oxo-2-vinylcyclohexyl pivalate

Guidance literature:: Multi-step reaction with 2 steps

1.1: copper(l) iodide / 0.17 h / -78 - 0 °C / Inert atmosphere; Schlenk technique

1.2: 0.33 h / -78 °C / Inert atmosphere

2.1: 3-chloro-benzenecarboperoxoic acid; sodium hydrogencarbonate / dichloromethane / 0 - 20 °C / Inert atmosphere

With copper(l) iodide; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/ol3031999

Reference yield:

: (1R)-2-methylene-5-(prop-1-en-2-yl)cyclohexane-1,3-diol

: 1416545-98-6
(1R,2S,5S)-2-methyl-4-oxo-5-(2-methyloxiran-2-yl)-4-oxo-2-vinylcyclohexyl pivalate

Guidance literature:: Multi-step reaction with 4 steps

1.1: triethylamine; dmap / dichloromethane / 8 h / 20 °C / Inert atmosphere

2.1: pyridinium chlorochromate; silica gel / dichloromethane / 16 h / 20 °C / Inert atmosphere

3.1: copper(l) iodide / 0.17 h / -78 - 0 °C / Inert atmosphere; Schlenk technique

3.2: 0.33 h / -78 °C / Inert atmosphere

4.1: 3-chloro-benzenecarboperoxoic acid; sodium hydrogencarbonate / dichloromethane / 0 - 20 °C / Inert atmosphere

With dmap; copper(l) iodide; silica gel; sodium hydrogencarbonate; triethylamine; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; In dichloromethane;
DOI:10.1021/ol3031999