(2S,3R,4R)-1-benzyloxy-2,4-bis(tert-butyldimethylsiloxy)-3,5-dimethylhexane

Base Information

Chemical Name:(2S,3R,4R)-1-benzyloxy-2,4-bis(tert-butyldimethylsiloxy)-3,5-dimethylhexane
CAS No.:642993-59-7
Molecular Formula:C₂₇H₅₂O₃Si₂
Molecular Weight:480.879
Hs Code.:

Synonyms:(2S,3R,4R)-1-benzyloxy-2,4-bis(tert-butyldimethylsiloxy)-3,5-dimethylhexane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,3R,4R)-1-benzyloxy-2,4-bis(tert-butyldimethylsiloxy)-3,5-dimethylhexane

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Technology Process of (2S,3R,4R)-1-benzyloxy-2,4-bis(tert-butyldimethylsiloxy)-3,5-dimethylhexane

There total 12 articles about (2S,3R,4R)-1-benzyloxy-2,4-bis(tert-butyldimethylsiloxy)-3,5-dimethylhexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 642993-55-3
(2S,3R,4R)-1-(benzyloxy)-3,5-dimethylhexane-2,4-diol

: 642993-59-7
(2S,3R,4R)-1-benzyloxy-2,4-bis(tert-butyldimethylsiloxy)-3,5-dimethylhexane

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; for 5h;
DOI:10.1016/j.tetlet.2012.02.067

Reference yield: 90.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 1-benzyloxy-3,5-dimethyl-hexane-2,4-diol

: 642993-59-7
(2S,3R,4R)-1-benzyloxy-2,4-bis(tert-butyldimethylsiloxy)-3,5-dimethylhexane

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at -78 - -35 ℃; for 3h;
DOI:10.1021/jo035068m

Reference yield:

: 426833-06-9
1-benzyloxy-3,5-dimethylhexane-2,4-dione

: 642993-59-7
(2S,3R,4R)-1-benzyloxy-2,4-bis(tert-butyldimethylsiloxy)-3,5-dimethylhexane

Guidance literature:: Multi-step reaction with 3 steps

1: (S,S)-ruthenium complex; Et₃N; HCO₂H / CH₂Cl₂ / 16 h / 20 °C

2: 90 percent / 2,6-lutidine / CH₂Cl₂ / 3 h / -78 - -35 °C

With 2,6-dimethylpyridine; formic acid; (S,S)-ruthenium; triethylamine; In dichloromethane;
DOI:10.1021/jo035068m