n-butyl(4-nitrophenyl) sulfane

Base Information

• Chemical Name: n-butyl(4-nitrophenyl) sulfane
• CAS No.: 27826-43-3
• Molecular Formula: C10H13 N O2 S
• Molecular Weight: 211.285
• Mol file: 27826-43-3.mol

Synonyms:Sulfide,butyl p-nitrophenyl (6CI,8CI); 4-Butylthionitrobenzene

Chemical Property of n-butyl(4-nitrophenyl) sulfane

Chemical Property:

• PSA: 71.12000
• LogP: 4.01020

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of n-butyl(4-nitrophenyl) sulfane

There total 18 articles about n-butyl(4-nitrophenyl) sulfane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

n-butanethiol (109-79-5) + para-nitrophenyl bromide (586-78-7) → butyl(4-nitrophenyl)sulfane (27826-43-3)

Guidance literature:

With 1,3-bis(4-chlorobenzyl)imidazolium chloride; potassium tert-butylate; nickel dichloride; In N,N-dimethyl-formamide; at 135 ℃; for 72h; Schlenk technique; Inert atmosphere;

DOI:10.1016/j.catcom.2017.02.007

Reference yield: 96.0%

1-iodo-butane (542-69-8) + di(p-nitrophenyl) disulfide (100-32-3) → butyl(4-nitrophenyl)sulfane (27826-43-3)

Guidance literature:

With water; rongalite; potassium carbonate; In N,N-dimethyl-formamide; for 0.25h;

DOI:10.1055/s-2006-950363

Reference yield: 94.0%

p-nitrobenzene iodide (636-98-6) + n-butanethiol (109-79-5) → butyl(4-nitrophenyl)sulfane (27826-43-3)

Guidance literature:

With iron(III) chloride hexahydrate; tetrabutylammomium bromide; L-proline; potassium hydroxide; In water; at 130 ℃; for 24h; Sealed tube;

DOI:10.1016/j.tetlet.2015.06.087

upstream raw materials:

n-Butyl chloride

4-nitrophenylthiolate

1-bromo-butane

di(p-nitrophenyl) disulfide

Downstream raw materials:

4-ntrophenyl(phenyl)amine

(4-Aminophenyl)-butyl-sulfon

4-butylsulfanyl-aniline; hydrochloride

4-butylsulfonylnitrobenzene