(E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne-dinickle⁽⁰⁾-1,5-cyclooctadiene

Base Information

• Chemical Name: (E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne-dinickle⁽⁰⁾-1,5-cyclooctadiene
• CAS No.: 1361408-36-7
• Molecular Formula: C₄₁H₄₉N₃Ni₂O₆S₃
• Molecular Weight: 893.435

Synonyms:(E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne-dinickle⁽⁰⁾-1,5-cyclooctadiene

Chemical Property of (E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne-dinickle⁽⁰⁾-1,5-cyclooctadiene

Chemical Property:

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Technology Process of (E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne-dinickle⁽⁰⁾-1,5-cyclooctadiene

There total 1 articles about (E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne-dinickle⁽⁰⁾-1,5-cyclooctadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + (E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne (916330-32-0) → (E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne-dinickle(0)-1,5-cyclooctadiene (1361408-36-7)

Guidance literature:

In tetrahydrofuran; (under Ar, Schlenk); soln. of ligand in THF combined with Ni-complex in THF at room temp., allowed to stand for 3 d; mother liquor removed, washed with Et2O, dried under vac.; elem. anal.;

DOI:10.1021/om201271y

Reference yield:

carbon monoxide (201230-82-2) + (E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne-dinickle(0)-1,5-cyclooctadiene (1361408-36-7) → tetracarbonyl nickel (13463-39-3,71564-36-8)

Guidance literature:

In tetrahydrofuran; THF soln. of Ni-complex stirred under CO; volatiles evapd. under vac., oxidized with H2O2;

DOI:10.1021/om201271y

upstream raw materials:

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

(E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne

Downstream raw materials:

tetracarbonyl nickel

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