trans-[Cr(5,7-dimethyl-6-benzyl-1,4,8,11-tetraazacyclotetradecane)(ONO)2]BF₄

Base Information

• Chemical Name: trans-[Cr(5,7-dimethyl-6-benzyl-1,4,8,11-tetraazacyclotetradecane)(ONO)2]BF₄
• CAS No.: 852328-87-1
• Molecular Formula: BF₄*C₁₉H₃₄CrN₆O₄
• Molecular Weight: 549.317
• Mol file: 852328-87-1.mol

Synonyms:trans-[Cr(5,7-dimethyl-6-benzyl-1,4,8,11-tetraazacyclotetradecane)(ONO)2]BF₄

Chemical Property of trans-[Cr(5,7-dimethyl-6-benzyl-1,4,8,11-tetraazacyclotetradecane)(ONO)2]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of trans-[Cr(5,7-dimethyl-6-benzyl-1,4,8,11-tetraazacyclotetradecane)(ONO)2]BF₄

There total 1 articles about trans-[Cr(5,7-dimethyl-6-benzyl-1,4,8,11-tetraazacyclotetradecane)(ONO)2]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.9%

sodium tetrafluoroborate (13755-29-8) + silver(I) nitrite (7783-99-5) + trans-[Cr(5,7-dimethyl-6-benzyl-1,4,8,11-tetraazacyclotetradecane)Cl2]Cl (852364-42-2,852291-07-7) → trans-[Cr(5,7-dimethyl-6-benzyl-1,4,8,11-tetraazacyclotetradecane)(ONO)2]BF4 (852328-87-1)

Guidance literature:

In water; byproducts: AgCl; a soln. of complex in water was heated to reflux, a hot aq. soln. of AgNO2 was added under subdued light, AgCl was filtered off, the mixt. was refluxed for 45 min, filtered, volatiles were removed., a soln. in H2O was filtered, treated with satd. NaBF4; NaNO2 was added, the soln. was sonicated, the soln. was cooled overnight, filtered;

DOI:10.1021/ic048311o

Reference yield:

trans-[Cr(5,7-dimethyl-6-benzyl-1,4,8,11-tetraazacyclotetradecane)(ONO)2]BF4 (852328-87-1) → trans-[Cr(IV)(5,7-dimethyl-6-benzyl-1,4,8,11-tetraazacyclotetradecane)(O)(ONO)](1+) + trans-[Cr(V)(5,7-dimethyl-6-benzyl-1,4,8,11-tetraazacyclotetradecane)(O)(ONO)](2+) + nitrogen(II) oxide (10102-43-9)

Guidance literature:

In water; Irradiation (UV/VIS); an aq. soln. of complex was phostolyzed under aerated conditions at ambient temp. using λ = 365 and 436 nm (Hg lamp);

DOI:10.1021/ic048311o

upstream raw materials:

sodium tetrafluoroborate

silver(I) nitrite

trans-[Cr(5,7-dimethyl-6-benzyl-1,4,8,11-tetraazacyclotetradecane)Cl₂]Cl

Downstream raw materials:

nitrogen(II) oxide