3-azidopropyl 3,4,6-tri-O-acetyl-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzyl-β-D-galactopyranosyl-(1->4)-2,4,6-tri-O-benzyl-β-D-glucopyranosyside

Base Information

• Chemical Name: 3-azidopropyl 3,4,6-tri-O-acetyl-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzyl-β-D-galactopyranosyl-(1->4)-2,4,6-tri-O-benzyl-β-D-glucopyranosyside
• CAS No.: 1143373-93-6
• Molecular Formula: C₉₉H₁₀₉Cl₃N₄O₂₅
• Molecular Weight: 1861.33
• Mol file: 1143373-93-6.mol

Synonyms:3-azidopropyl 3,4,6-tri-O-acetyl-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzyl-β-D-galactopyranosyl-(1->4)-2,4,6-tri-O-benzyl-β-D-glucopyranosyside

Chemical Property of 3-azidopropyl 3,4,6-tri-O-acetyl-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzyl-β-D-galactopyranosyl-(1->4)-2,4,6-tri-O-benzyl-β-D-glucopyranosyside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-azidopropyl 3,4,6-tri-O-acetyl-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzyl-β-D-galactopyranosyl-(1->4)-2,4,6-tri-O-benzyl-β-D-glucopyranosyside

There total 1 articles about 3-azidopropyl 3,4,6-tri-O-acetyl-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzyl-β-D-galactopyranosyl-(1->4)-2,4,6-tri-O-benzyl-β-D-glucopyranosyside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

3-azidopropyl (2,3,6-O-tri-O-benzyl-β-D-galactopyranosyl)-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside (646058-15-3) + p-tolyl 3,4,6-tri-O-acetyl-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzy-1-thio-β-D-galactopyranoside (1143373-78-7) → 3-azidopropyl 3,4,6-tri-O-acetyl-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzyl-β-D-galactopyranosyl-(1->4)-2,4,6-tri-O-benzyl-β-D-glucopyranosyside (1143373-93-6) + 3-azidopropyl 3,4,6-tri-O-acetyl-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzyl-β-D-galactopyranosyl-(1->4)-2,4,6-tri-O-benzyl-β-D-glucopyranosyside (1143374-07-5)

Guidance literature:

p-tolyl 3,4,6-tri-O-acetyl-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzy-1-thio-β-D-galactopyranoside; With p-methylbenzenesulfenyl chloride; silver trifluoromethanesulfonate; In diethyl ether; dichloromethane; at -78 ℃; Molecular sieve;

3-azidopropyl (2,3,6-O-tri-O-benzyl-β-D-galactopyranosyl)-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside; In diethyl ether; dichloromethane; at -78 - -20 ℃; for 2h;

DOI:10.1002/adsc.200800129

Reference yield:

3-azidopropyl 3,4,6-tri-O-acetyl-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzyl-α-D-galactopyranosyl-(1->4)-2,3,6-tri-O-benzyl-β-D-galactopyranosyl-(1->4)-2,4,6-tri-O-benzyl-β-D-glucopyranosyside (1143373-93-6) → C96H108N4O23

Guidance literature:

With water; sodium methylate; In tetrahydrofuran; at 50 ℃;

DOI:10.1002/adsc.200800129

upstream raw materials:

3-azidopropyl (2,3,6-O-tri-O-benzyl-β-D-galactopyranosyl)-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

p-tolyl 3,4,6-tri-O-acetyl-2-(2,2,2-trichloroethoxycarbonylamino)-2-deoxy-β-D-galactopyranosyl-(1->3)-2,4,6-tri-O-benzy-1-thio-β-D-galactopyranoside