(μ-bromo)dibromo[η5-2-mesitylindenyl]zirconium dimer

Base Information

Chemical Name:(μ-bromo)dibromo[η5-2-mesitylindenyl]zirconium dimer
CAS No.:1131543-59-3
Molecular Formula:C₃₆H₃₄Br₆Zr₂
Molecular Weight:1128.54
Hs Code.:

Synonyms:(μ-bromo)dibromo[η5-2-mesitylindenyl]zirconium dimer

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Chemical Property of (μ-bromo)dibromo[η5-2-mesitylindenyl]zirconium dimer

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Technology Process of (μ-bromo)dibromo[η5-2-mesitylindenyl]zirconium dimer

There total 1 articles about (μ-bromo)dibromo[η5-2-mesitylindenyl]zirconium dimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 19756-04-8
tetrakis(dimethylamido)zirconium (IV)

: 749870-00-6
2-(2,4,6-trimethylphenyl)indene

: 2857-97-8
trimethylsilyl bromide

: 1131543-59-3
(μ-bromo)dibromo[η5-2-mesitylindenyl]zirconium dimer

Guidance literature:: In toluene; (Ar); stirring a mixt. of Zr compd. and ligand in ether for 12 h at roomtemp., evapn., addn. of toluene, addn. of Si compd., at room temp., sti rring for 12 h; evapn., addn. of toluene and hexanes, filtration, washing ppt. with hexanes, drying in vac.; elem. anal.;
DOI:10.1021/om8010257

Reference yield: 58.0%

: 869063-58-1
1-(1H-inden-2-yl)-1H-indole

: 1131543-59-3
(μ-bromo)dibromo[η5-2-mesitylindenyl]zirconium dimer

: 1131543-61-7
[η5-2-mesitylindenyl][η5-2-(1H-indol-1-yl)indenyl]zirconium dibromide

Guidance literature:: With n-butyllithium; In diethyl ether; hexane; toluene; (Ar); addn. of Li compd. in hexanes to a soln. of ligand in ether at room temp., stirring overnight, addn. to a soln. of Zr complex in toluene at -35°C, stirring for 0.5 h, then overnight at room temp.; evapn., extn. with toluene, filtration through PTFE membrane, concn., reflux with hexanes, cooling to -30°C, washing ppt. with hexanes, drying in vac; elem. anal.;
DOI:10.1021/om8010257

Reference yield: 43.0%

: 869063-56-9
1-(1H-inden-2-yl)-1H-pyrrole

: 1131543-59-3
(μ-bromo)dibromo[η5-2-mesitylindenyl]zirconium dimer

: 1131543-60-6
[η5-2-mesitylindenyl][η5-2-(1H-pyrrol-1-yl)indenyl]zirconium dibromide

Guidance literature:: With n-butyllithium; In diethyl ether; hexane; toluene; (Ar); addn. of Li compd. in hexanes to a soln. of ligand in ether at room temp., stirring overnight, addn. to a soln. of Zr complex in toluene at -35°C, stirring for 0.5 h, then overnight at room temp.; evapn., extn. with toluene, filtration through PTFE membrane, concn., filtration, washing ppt. with toluene, hexanes, drying in vac.; elem. anal.;
DOI:10.1021/om8010257