Benzenamine, N-[(4-methylphenyl)methylene]-

Base Information

• Chemical Name: Benzenamine, N-[(4-methylphenyl)methylene]-
• CAS No.: 2362-77-8
• Molecular Formula: C14H13 N
• Molecular Weight: 195.264
• Hs Code.: 2925290090
• European Community (EC) Number: 664-331-8
• DSSTox Substance ID: DTXSID30335534,DTXSID901274451
• Nikkaji Number: J2.454.182G,J102.138I
• Mol file: 2362-77-8.mol

Synonyms:2362-77-8;Benzenamine, N-[(4-methylphenyl)methylene]-;N-(p-Methylbenzylidene)aniline;1-(4-methylphenyl)-N-phenylmethanimine;N-(4-Methylbenzylidene)aniline;Aniline, N-(p-methylbenzylidene)-;(E)-N-(4-Methylbenzylidene)aniline;15486-64-3;(p-Methylbenzylidene)-phenylamine;N-[(4-Methylphenyl)methylidene]aniline #;SCHEMBL443279;DTXSID30335534;DTXSID901274451;N-[(E)-4-Methylbenzylidene]aniline;AKOS006242420;N-[(4-Methylphenyl)methylene]benzenamine;(E)-N-[(4-Methylphenyl)methylidene]aniline;1613-98-5

Chemical Property of Benzenamine, N-[(4-methylphenyl)methylene]-

Chemical Property:

• Melting Point: 46.5-48 °C
• Boiling Point: 320 °C(Press: 747 Torr)
• PKA: 3.62±0.30(Predicted)
• PSA: 12.36000
• Density: 1.046 g/cm3(Temp: 25 °C)
• LogP: 3.74560
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 195.104799419
• Heavy Atom Count: 15
• Complexity: 195

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)C=NC2=CC=CC=C2

Technology Process of Benzenamine, N-[(4-methylphenyl)methylene]-

There total 45 articles about Benzenamine, N-[(4-methylphenyl)methylene]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

4-methyl-benzaldehyde (104-87-0) + aniline (62-53-3) → (4-methylbenzylidene)phenylamine (2362-77-8)

Guidance literature:

With HC(CMeN(2,6-Et₂C₆H₃)₂₎Al(μ-S)₂AlHC(CMeN(2,6-Et₂C₆H₃))₂; In chloroform-d1; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.ica.2017.05.034

Reference yield: 95.0%

4-methyl-benzaldehyde (104-87-0) + nitrobenzene (98-95-3,26969-40-4) → (4-methylbenzylidene)phenylamine (2362-77-8)

Guidance literature:

With hydrogenchloride; iron; In ethanol; water; at 65 ℃;

DOI:10.1055/s-2007-986668

Reference yield: 95.0%

aniline (62-53-3) + para-methylbenzylamine (104-84-7) → (4-methylbenzylidene)phenylamine (2362-77-8)

Guidance literature:

With oxygen; iron(II) bromide; In neat (no solvent); at 110 ℃; for 6h; Green chemistry;

DOI:10.1007/s10562-016-1789-3

upstream raw materials:

4-methyl-benzaldehyde

aniline

N-(4-methylbenzyl)aniline

1-(Bromo-p-tolyl-methyl)-pyridinium; bromide

Downstream raw materials:

N-([2]pyridyl-p-tolyl-methyl)-aniline

dimethyl (4-methylphenyl)(N-phenylamino)methylphosphonate

N-(4-methylbenzyl)aniline

N₁,N₂-di(phenyl)-1,2-di(4'-methylphenyl)-1,2-ethanediamine