[(pentamethylcyclopentadienyl)2Ir2Cl2(μ-N,N'-bis(4-methylphenyl)oxamidato)]

Base Information

Chemical Name:[(pentamethylcyclopentadienyl)2Ir2Cl2(μ-N,N'-bis(4-methylphenyl)oxamidato)]
CAS No.:1225042-66-9
Molecular Formula:C₃₆H₄₄Cl₂Ir₂N₂O₂
Molecular Weight:992.104
Hs Code.:

Synonyms:[(pentamethylcyclopentadienyl)2Ir2Cl2(μ-N,N'-bis(4-methylphenyl)oxamidato)]

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Chemical Property of [(pentamethylcyclopentadienyl)2Ir2Cl2(μ-N,N'-bis(4-methylphenyl)oxamidato)]

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Technology Process of [(pentamethylcyclopentadienyl)2Ir2Cl2(μ-N,N'-bis(4-methylphenyl)oxamidato)]

There total 1 articles about [(pentamethylcyclopentadienyl)2Ir2Cl2(μ-N,N'-bis(4-methylphenyl)oxamidato)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.6%

: 12354-84-6,12354-85-7
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

: 3299-61-4
N,N'-Di-p-tolyloxalamide

: 1225042-66-9
[(pentamethylcyclopentadienyl)2Ir2Cl2(μ-N,N'-bis(4-methylphenyl)oxamidato)]

Guidance literature:: With C₄H₉Li; In tetrahydrofuran; (N2, Schlenk technique); addn. of butyllithium to THF soln. of oxamide deriv. at -78°C, stirring for 2 h with warming to room temp., addn. to suspn. of iridium compd. in THF, stirring overnight aat 50°C; evapn., extn. (CH2Cl2), evapn., washing with diethyl ether, elem. anal.;
DOI:10.1021/om901125r

Reference yield: 99.0%

: 1225042-66-9
[(pentamethylcyclopentadienyl)2Ir2Cl2(μ-N,N'-bis(4-methylphenyl)oxamidato)]

: [(pentamethylcyclopentadienyl)4Ir4(μ-N,N'-bis(4-methylphenyl)oxamidato)2(μ-rctt-tetrakis(4-pyridyl)cyclobutane)](OTf)4

Guidance literature:: In neat (no solvent, solid phase); Irradiation (UV/VIS); (N2, Schlenk technique); irradiation of iridium compd. with 300 W broad Hg lamp for 40 h; elem. anal.;
DOI:10.1021/om901125r

Reference yield: 89.0%

: 1225042-66-9
[(pentamethylcyclopentadienyl)2Ir2Cl2(μ-N,N'-bis(4-methylphenyl)oxamidato)]

: 2923-28-6
silver trifluoromethanesulfonate

: 13362-78-2
trans-1,2-bis(pyridin-4-yl)ethene

: [(pentamethylcyclopentadienyl)4Ir4(μ-N,N'-bis(4-methylphenyl)oxamidato)2(μ-4,4'-1,2-bis(4-pyridyl)ethylene)2](OTf)4

Guidance literature:: In methanol; (N2, Schlenk technique); addn. of 2 equiv. of silver compd. to suspn. ofiridium compd. in methanol at room temp., stirring for 4 h, filtration, addn. of pyridine deriv., stirring for 15 h; filtration, evapn., extn. (CH2Cl2), evapn., washing with diethyl ether, drying in vac., elem. anal.;
DOI:10.1021/om901125r