Mn(IV)(O)(OH)(tetramesitylporphyrin)

Base Information

Chemical Name:Mn(IV)(O)(OH)(tetramesitylporphyrin)
CAS No.:108535-08-6
Molecular Formula:C₅₆H₅₃MnN₄O₂
Molecular Weight:869
Hs Code.:

Synonyms:Mn(IV)(O)(OH)(tetramesitylporphyrin)

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Chemical Property of Mn(IV)(O)(OH)(tetramesitylporphyrin)

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Technology Process of Mn(IV)(O)(OH)(tetramesitylporphyrin)

There total 9 articles about Mn(IV)(O)(OH)(tetramesitylporphyrin) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

: tetra-n-butylammonium hydroxide

: 85939-49-7
(5,10,15,20-tetramesitylporphyrinato)manganese(III) chloride

: 108535-08-6
hydroxo-oxo(5,10,15,20-tetramesitylporphyrinato)manganese(IV)

Guidance literature:: With TBAP; In dichloromethane; Electrolysis; electrolysis at +1.20 V, pipeting of react. soln. in -78°C pentane and standing for 5 min; filtering and chromy. (basic alumina) at -78°C, evapn. of the solvent, vac. drying of the solid at low temp.;
DOI:10.1021/ja00234a009

Reference yield:

: 85939-49-7
(5,10,15,20-tetramesitylporphyrinato)manganese(III) chloride

: 108535-08-6
Mn(IV)(O)(OH)(tetramesitylporphyrin)

Guidance literature:: With tetramethyl ammoniumhydroxide; 3-chloro-benzenecarboperoxoic acid; In methanol; dichloromethane; 0°C, 2 equivalents Me4NOH in MeOH, TBA(OH) added, stirred for 3 min.; Alumina chromatography, -78°C.;
DOI:10.1021/ja00221a010

Reference yield:

: 104025-52-7
ClMn(III)(tetramesitylporphyrin) cation radical

: 108535-08-6
Mn(IV)(O)(OH)(tetramesitylporphyrin)

Guidance literature:: With tetra(n-butyl)ammonium hydroxide; In dichloromethane; water; Addn. of TBA(OH) soln. (40% in H2O) to soln. of complex at -20°C.; not isolated, detn. by UV/VIS spectroscopy;
DOI:10.1021/ja00221a010