METHYL CITRONELLATE

Base Information

• Chemical Name: METHYL CITRONELLATE
• CAS No.: 2270-60-2
• Molecular Formula: C11H20 O2
• Molecular Weight: 184.279
• Hs Code.: 2916190090
• Mol file: 2270-60-2.mol

Synonyms:Citronellicacid, methyl ester (6CI);Methyl (?à)-citronellate;Methyl 3,7-dimethyl-6-octenoate;Methyl citronellate;

Chemical Property of METHYL CITRONELLATE

Chemical Property:

• Vapor Pressure: 0.078mmHg at 25°C
• Refractive Index: 1.44
• Boiling Point: 227.4°Cat760mmHg
• Flash Point: 76.4°C
• PSA: 26.30000
• Density: 0.888g/cm³
• LogP: 2.93200

Purity/Quality:

99% ^*data from raw suppliers

METHYL CITRONELLATE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHYL CITRONELLATE

There total 25 articles about METHYL CITRONELLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

methanol (67-56-1) + 3,7-dimethyl-oct-6-enal (106-23-0,26489-02-1) → methyl 3,7-dimethyloct-6-enoate (2270-60-2)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; 2,2,2-Trifluoroacetophenone; 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene; In 1,4-dioxane; at 30 ℃; for 12h; Inert atmosphere; Glovebox;

DOI:10.1002/anie.201410322

Reference yield: 95.0%

methyl nerate (1862-61-9) → methyl 3,7-dimethyloct-6-enoate (2270-60-2)

Guidance literature:

With ammonium formate; palladium on activated charcoal; In methanol; at 25 ℃; for 1h;

DOI:10.1016/S0040-4039(00)78461-9

Reference yield: 82.0%

methyl geranate (1189-09-9,1862-61-9,2349-14-6) → methyl 3,7-dimethyloct-6-enoate (2270-60-2)

Guidance literature:

With hydrogen; platinum; In ethanol; Ambient temperature;

upstream raw materials:

methyl geranate

triethylamine

diazomethane

racemic citronellic acid

Downstream raw materials:

Citronellol

(+/-)-iridomyrmecin

Methyl (1α,2α,5β)-2-Methyl-5-(1-methylethenyl)cyclohexanecarboxylate

Methyl (1β,2α,5β)-2-Methyl-5-(1-methylethenyl)cyclohexanecarboxylate