2-[4-(benzylsulfanyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

• Chemical Name: 2-[4-(benzylsulfanyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS No.: 1029438-24-1
• Molecular Formula: C₁₉H₂₃BO₂S
• Molecular Weight: 326.267
• Mol file: 1029438-24-1.mol

Synonyms:2-[4-(benzylsulfanyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property of 2-[4-(benzylsulfanyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 2-[4-(benzylsulfanyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 6 articles about 2-[4-(benzylsulfanyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

C16H24BN3O2 + benzyl chloride (100-44-7) → 2-[4-(benzylsulfanyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1029438-24-1)

Guidance literature:

benzyl chloride; With [2,2]bipyridinyl; copper(ll) sulfate pentahydrate; Sodium thiosulfate pentahydrate; In water; at 80 ℃; for 2h; Schlenk technique;

C₁₆H₂₄BN₃O₂; With boron trifluoride diethyl etherate; In water; at 20 ℃; for 12h; Schlenk technique;

DOI:10.1039/c4cc08367a

Reference yield: 62.0%

1-[2-[4-(benzylsulfanyl)phenyl]diazen-1-yl]pyrrolidine (1394130-72-3) + bis(pinacol)diborane (73183-34-3) → 2-[4-(benzylsulfanyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1029438-24-1)

Guidance literature:

With boron trifluoride diethyl etherate; In acetonitrile; at 0 - 20 ℃; for 0.25h; Inert atmosphere;

DOI:10.1021/ol302024m

Reference yield: 51.0%

benzyl chloride (100-44-7) + 4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)aniline (214360-73-3) → 2-[4-(benzylsulfanyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1029438-24-1)

Guidance literature:

benzyl chloride; With [2,2]bipyridinyl; copper(ll) sulfate pentahydrate; sodium thiosulfate pentahydrate; In methanol; water; at 80 ℃; for 2h; Schlenk technique;

4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)aniline; With tert.-butylnitrite; In methanol; water; at 0 - 20 ℃; for 4.66667h; Schlenk technique;

DOI:10.1021/ol5009747

upstream raw materials:

4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzenethiol

benzyl bromide

benzyl 4-aminophenyl sulfide

1-[2-[4-(benzylsulfanyl)phenyl]diazen-1-yl]pyrrolidine