2-oxo-2-(pyren-1-yl)ethyl phenyl carbonate

Base Information

• Chemical Name: 2-oxo-2-(pyren-1-yl)ethyl phenyl carbonate
• CAS No.: 1449331-31-0
• Molecular Formula: C₂₅H₁₆O₄
• Molecular Weight: 380.4
• Mol file: 1449331-31-0.mol

Synonyms:2-oxo-2-(pyren-1-yl)ethyl phenyl carbonate

Chemical Property of 2-oxo-2-(pyren-1-yl)ethyl phenyl carbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-oxo-2-(pyren-1-yl)ethyl phenyl carbonate

There total 7 articles about 2-oxo-2-(pyren-1-yl)ethyl phenyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

2-hydroxy-1-(pyren-1-yl)ethanone (1192592-19-0) + phenyl chloroformate (1885-14-9) → 2-oxo-2-(pyren-1-yl)ethyl phenyl carbonate (1449331-31-0)

Guidance literature:

With dmap; In dichloromethane; at 20 ℃;

DOI:10.1039/c2pp25091h

Reference yield:

benzyl 2-oxo-2-(pyren-1-yl)ethyl carbonate (1449331-28-5) → 2-oxo-2-(pyren-1-yl)ethyl phenyl carbonate (1449331-31-0)

Guidance literature:

Multi-step reaction with 2 steps

1: water / acetonitrile / pH 7.5 / Photolysis; Inert atmosphere

2: dmap / dichloromethane / 20 °C

With dmap; water; In dichloromethane; acetonitrile;

DOI:10.1039/c2pp25091h

Reference yield:

2-isopropyl-5-methylcyclohexyl 2-oxo-2-(pyren-1-yl)ethyl carbonate (1449331-29-6) → 2-oxo-2-(pyren-1-yl)ethyl phenyl carbonate (1449331-31-0)

Guidance literature:

Multi-step reaction with 2 steps

1: water / acetonitrile / pH 7.5 / Photolysis; Inert atmosphere

2: dmap / dichloromethane / 20 °C

With dmap; water; In dichloromethane; acetonitrile;

DOI:10.1039/c2pp25091h

upstream raw materials:

2-hydroxy-1-(pyren-1-yl)ethanone

phenyl chloroformate

1-acetylpyrene

benzyl 2-oxo-2-(pyren-1-yl)ethyl carbonate

Downstream raw materials:

phenyl chloroformate

1-acetylpyrene

2-hydroxy-1-(pyren-1-yl)ethanone

phenol

Refernces