(R)-5-(2-(benzyloxy)pent-4-en-1-yl)-7-methoxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one

Base Information

Chemical Name:(R)-5-(2-(benzyloxy)pent-4-en-1-yl)-7-methoxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one
CAS No.:1394226-62-0
Molecular Formula:C₂₃H₂₆O₅
Molecular Weight:382.456
Hs Code.:

Synonyms:(R)-5-(2-(benzyloxy)pent-4-en-1-yl)-7-methoxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one

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Chemical Property of (R)-5-(2-(benzyloxy)pent-4-en-1-yl)-7-methoxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one

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Technology Process of (R)-5-(2-(benzyloxy)pent-4-en-1-yl)-7-methoxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one

There total 6 articles about (R)-5-(2-(benzyloxy)pent-4-en-1-yl)-7-methoxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 882980-43-0
2-benzyloxy-1-methylpyridinium triflate

: 1394226-61-9
(R)-5-(2-hydroxypent-4-en-1-yl)-7-methoxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one

: 1394226-62-0
(R)-5-(2-(benzyloxy)pent-4-en-1-yl)-7-methoxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one

Guidance literature:: With magnesium oxide; In benzene; at 83 ℃; for 24h;
DOI:10.1021/jo301167a

Reference yield:

: 137571-73-4
5,7-dihydroxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one

: 1394226-62-0
(R)-5-(2-(benzyloxy)pent-4-en-1-yl)-7-methoxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one

Guidance literature:: Multi-step reaction with 6 steps

1.1: triphenylphosphine / tetrahydrofuran / 0.08 h / 0 °C

1.2: 4 h / 0 °C

2.1: pyridine / 24 h / 0 °C

3.1: cesium fluoride; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran / 0.5 h

3.2: 24 h / Reflux

4.1: ozone / dichloromethane; methanol / -78 °C

5.1: diethyl ether / 1 h / -78 °C / Inert atmosphere

6.1: magnesium oxide / benzene / 24 h / 83 °C

With pyridine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; magnesium oxide; ozone; triphenylphosphine; cesium fluoride; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; benzene; 3.1: |Suzuki Coupling / 3.2: |Suzuki Coupling;
DOI:10.1021/jo301167a

Reference yield:

: 532394-17-5
7-methoxy-2,2-dimethyl-5-(trifluoromethylsulfonyloxy)benzo[1,3]dioxin-4-one

: 1394226-62-0
(R)-5-(2-(benzyloxy)pent-4-en-1-yl)-7-methoxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one

Guidance literature:: Multi-step reaction with 4 steps

1.1: cesium fluoride; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran / 0.5 h

1.2: 24 h / Reflux

2.1: ozone / dichloromethane; methanol / -78 °C

3.1: diethyl ether / 1 h / -78 °C / Inert atmosphere

4.1: magnesium oxide / benzene / 24 h / 83 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; magnesium oxide; ozone; cesium fluoride; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; benzene; 1.1: |Suzuki Coupling / 1.2: |Suzuki Coupling;
DOI:10.1021/jo301167a