bis(triphenylphosphane)(4,5-diazafluorenide)dihydridorhodium(III)

Base Information

• Chemical Name: bis(triphenylphosphane)(4,5-diazafluorenide)dihydridorhodium(III)
• CAS No.: 1208005-92-8
• Molecular Formula: C₄₇H₃₉N₂P₂Rh
• Molecular Weight: 796.693
• Mol file: 1208005-92-8.mol

Synonyms:bis(triphenylphosphane)(4,5-diazafluorenide)dihydridorhodium(III)

Chemical Property of bis(triphenylphosphane)(4,5-diazafluorenide)dihydridorhodium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(triphenylphosphane)(4,5-diazafluorenide)dihydridorhodium(III)

There total 3 articles about bis(triphenylphosphane)(4,5-diazafluorenide)dihydridorhodium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

bis(triphenylphosphane)(4,5-diazafluorene)dihydridorhodium(III) chloride - dichloromethane (1/0.125) → bis(triphenylphosphane)(4,5-diazafluorenide)dihydridorhodium(III) (1208005-92-8)

Guidance literature:

With NaH; In tetrahydrofuran; byproducts: NaCl; under Ar, Schlenk techniques; 1.6 equiv. of NaH (60% in mineral iol) added to suspn. of Rh complex in THF, mixt. stirred for 1 d; soln. filtered through Celite), filtrate dried under vac.; elem. anal.;

DOI:10.1002/ejic.200801195

Reference yield: 99.0%

bis(triphenylphosphane)(4,5-diazafluorenide)rhodium(I) + hydrogen (1333-74-0) → bis(triphenylphosphane)(4,5-diazafluorenide)dihydridorhodium(III) (1208005-92-8)

Guidance literature:

In not given; Rh complex treated with H2 (1 atm.);

DOI:10.1002/ejic.200801195

Reference yield:

bis(triphenylphosphane)(4,5-diazafluorenide)rhodium(I) + C48H39N2O2P2Rh → bis(triphenylphosphane)(4,5-diazafluorenide)dihydridorhodium(III) (1208005-92-8) + C84H68N2O2P4Rh2

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 2h; Sealed tube;

DOI:10.1021/om500278a

upstream raw materials:

hydrogen