Technology Process of (ethoxycarbonyl)(5,10,15,20-tetraphenylporphinato)cobalt(III)
There total 1 articles about (ethoxycarbonyl)(5,10,15,20-tetraphenylporphinato)cobalt(III) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium amalgam;
In
tetrahydrofuran;
under Ar, Co-compd. in THF reduced for 1 h with 1% Na#Hg, 34 equiv of ethyl chloroformate added to mixt., stirred for 5 min; filtered, taken to dryness by rotary evapn., triturated with CHCl3, filtered, pptd. from soln. by adding petroleum ether, filtered, recrystd. from CHCl3-petroleum ether; elem. anal.;
DOI:10.1021/ic50226a061
- Guidance literature:
-
With
tert-butylammonium hexafluorophosphate(V);
In
dichloromethane;
Electrolysis; under Ar, soln. of Co-compd. in CH2Cl2 contg. 0.05 M n-Bu4NPF6 oxidizedat 1.08 V at room temp.; taken to dryness, dissolved in min. vol. of CH2Cl2, petroleum ether added, chromd. on thin layer silica gel (CH2Cl2-MeOH), product removed fromplate, crystd. from CH2Cl2-petroleum ether;
DOI:10.1021/ic50226a061
- Guidance literature:
-
With
tert-butylammonium hexafluorophosphate(V);
In
dichloromethane;
Electrolysis; under Ar, soln. of Co-compd. in CH2Cl2 contg. 0.05 M n-Bu4NPF6 oxidizedat 1.08 V at -40°C; without isolation;
DOI:10.1021/ic50226a061
