POLY(VINYL PHENYL KETONE)

Base Information

• Chemical Name: POLY(VINYL PHENYL KETONE)
• CAS No.: 26742-84-7
• Molecular Formula: [-CH2CH(COC6H5)-]n
• Molecular Weight: 132.16
• Mol file: 26742-84-7.mol

Synonyms:POLY(VINYL PHENYL KETONE)

Chemical Property of POLY(VINYL PHENYL KETONE)

Chemical Property:

• Density: 1.19 g/mL at 25 °C(lit.)

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of POLY(VINYL PHENYL KETONE)

There total 233 articles about POLY(VINYL PHENYL KETONE) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

1-Phenylprop-1-yne (673-32-5) → Phenyl vinyl ketone (768-03-6,26742-84-7) + 1-Phenylpropane-1,2-dione (579-07-7)

Guidance literature:

With 2,6-dichloropyridine N-oxide; [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold bis(trifluoromethanesulfonyl)imidate; at 60 ℃; regioselective reaction;

DOI:10.1002/anie.201504511

Reference yield: 45.0%

3-chloropropiophenone (936-59-4) + 4-isopropyl-2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxylic acid diethyl ester (1539-32-8) → 4-methyl-1-phenylpentan-1-one (2050-07-9) + Phenyl vinyl ketone (768-03-6,26742-84-7)

Guidance literature:

With di-tert-butyl peroxide; α,α,α-trifluorotoluene; copper; at 100 ℃; for 48h; Reagent/catalyst; Inert atmosphere;

DOI:10.1021/acs.joc.9b02323

Reference yield: 27.0%

1,3,6-triphenyl-1,4,5,6-tetrahydropyridazine (137116-92-8) → benzaldehyde (100-52-7) + 4-benzoyl-2-phenyl-1,2,3,4-tetrahydroquinoline (137117-04-5,137117-05-6) + Phenyl vinyl ketone (768-03-6,26742-84-7)

Guidance literature:

With PPA; Polyphosphoric acid (PPA); at 110 ℃; for 0.5h; Yields of byproduct given;

upstream raw materials:

carbon disulfide

ethene

β-Propiolactone

benzene

Downstream raw materials:

1,3-dimethyl-7-(3-oxo-3-phenyl-propyl)-3,7-dihydro-purine-2,6-dione

nepenthone

phenyl-(6-phenyl-3,4-dihydro-2H-pyran-2-yl)-ketone thiosemicarbazone

cyclohex-3-en-1-yl(phenyl)methanone