(1R,2Z,4S)-{4-[(2-methoxyethoxy)methoxy]-1-phenyl-2-penten-1-yl} acetate

Base Information

Chemical Name:(1R,2Z,4S)-{4-[(2-methoxyethoxy)methoxy]-1-phenyl-2-penten-1-yl} acetate
CAS No.:875534-24-0
Molecular Formula:C₁₇H₂₄O₅
Molecular Weight:308.375
Hs Code.:

Synonyms:(1R,2Z,4S)-{4-[(2-methoxyethoxy)methoxy]-1-phenyl-2-penten-1-yl} acetate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,2Z,4S)-{4-[(2-methoxyethoxy)methoxy]-1-phenyl-2-penten-1-yl} acetate

Chemical Property:

Purity/Quality:

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Technology Process of (1R,2Z,4S)-{4-[(2-methoxyethoxy)methoxy]-1-phenyl-2-penten-1-yl} acetate

There total 1 articles about (1R,2Z,4S)-{4-[(2-methoxyethoxy)methoxy]-1-phenyl-2-penten-1-yl} acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.3%

: 108-24-7
acetic anhydride

: 114091-75-7
(1R,2Z,4S)-4-<(2-Methoxyethoxy)methoxy>-1-phenyl-2-penten-1-ol

: 875534-24-0
(1R,2Z,4S)-{4-[(2-methoxyethoxy)methoxy]-1-phenyl-2-penten-1-yl} acetate

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 20 ℃; for 23h;
DOI:10.1002/adsc.200700409

Reference yield: 83.0%

: 875534-24-0
(1R,2Z,4S)-{4-[(2-methoxyethoxy)methoxy]-1-phenyl-2-penten-1-yl} acetate

: 98-86-2
acetophenone

: 875534-25-1
(3S,4E,6S)-6-[(methoxyethoxy)methoxy]-1,3-diphenyl-4-hepten-1-one

Guidance literature:: acetophenone; With n-butyllithium; diisopropylamine; lithium chloride; In tetrahydrofuran; hexane; at -78 ℃; Inert atmosphere;

(1R,2Z,4S)-{4-[(2-methoxyethoxy)methoxy]-1-phenyl-2-penten-1-yl} acetate; With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; chloroform; In tetrahydrofuran; hexane; at -78 ℃; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/adsc.200700409

Reference yield:

: 875534-24-0
(1R,2Z,4S)-{4-[(2-methoxyethoxy)methoxy]-1-phenyl-2-penten-1-yl} acetate

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: (2S,1'R,2'E,4'S)-2-{4-[(2-methoxyethoxy)methoxy]-1-phenylpent-2-en-1-yl}cyclohexanone

: (2R,1'R,2'E,4'S)-2-{4-[(2-methoxyethoxy)methoxy]-1-phenylpent-2-en-1-yl}cyclohexanone

Guidance literature:: cyclohexanone; With n-butyllithium; diisopropylamine; lithium chloride; In tetrahydrofuran; hexane; at -78 ℃; Inert atmosphere;

(1R,2Z,4S)-{4-[(2-methoxyethoxy)methoxy]-1-phenyl-2-penten-1-yl} acetate; With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; chloroform; In tetrahydrofuran; hexane; at -78 ℃; optical yield given as %de; diastereoselective reaction;
DOI:10.1002/adsc.200700409