Mn(CO)4(S₂CN(H)CH₃)

Base Information

Chemical Name:Mn(CO)4(S₂CN(H)CH₃)
CAS No.:69057-58-5
Molecular Formula:C₆H₄MnNO₄S₂
Molecular Weight:273.172
Hs Code.:

Mn(CO)4(S<sub>2</sub>CN(H)CH<sub>3</sub>)

Synonyms:Mn(CO)4(S₂CN(H)CH₃)

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Chemical Property of Mn(CO)4(S₂CN(H)CH₃)

Chemical Property:

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Technology Process of Mn(CO)4(S₂CN(H)CH₃)

There total 2 articles about Mn(CO)4(S₂CN(H)CH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 1.0%

: 14516-54-2
bromopentacarbonylmanganese(I)

: 74-93-1
methylthiol

: 7646-69-7
sodium hydride

: 556-61-6
methyl thioisocyanate

: 10170-69-1
dimanganese decacarbonyl

: 21321-38-0
[(Mn(CO)4(μ-SMe))2]

: 69057-58-5
Mn(CO)4(S₂CN(H)CH₃)

: 55173-11-0
Mn(CO)4(S₂CSCH₃)

: 57417-84-2
di-μ-methylimino(methylthio)methanethiolato-bis(tricarbonylmanganese)

Guidance literature:: In tetrahydrofuran; absence of air and moisture; bubbling MeSH through NaH suspn. (0°C, 2 min), addn. of excess MeNCS, addn. of Mn-complex, warming to room temp. during 2 h; evapn., extn. into CH2Cl2, evapn., chromy. (SiO2, hexane, then CH2Cl2/hexane=1:9, 1:4, 1:2); IR spectroscopy;
DOI:10.1039/DT9780001247

Reference yield:

: Mn(CO)4(C(O)NHC₆H₁₁)(NH₂C₆H₁₁)

: 556-61-6
methyl thioisocyanate

: 69057-58-5
Mn(CO)4(S₂CN(H)CH₃)

: 81174-25-6
Mn(CO)3(CNC₆H₁₁)S₂CN(H)CH₃

Guidance literature:: In tetrahydrofuran; byproducts: CH3NHC(S)NHC6H11; inert atmosphere, complex in THF was treated with isothiocyanate at room temp., mixt. was stirred for several hours; mixt. was filtered, solvent was evapd., residue was slurried in CH2Cl2 and chromd., crystd. from CH2Cl2 by addition of hexane; elem. anal.;
DOI:10.1016/S0020-1693(00)90268-8