[(1,1'-bis(diphenylphosphino)ferrocene)Cu(N,N'-di-n-butyl-2-amino-5-alcoholate-1,4-benzoquinonemonoiminium(-1H))]

Base Information

• Chemical Name: [(1,1'-bis(diphenylphosphino)ferrocene)Cu(N,N'-di-n-butyl-2-amino-5-alcoholate-1,4-benzoquinonemonoiminium(-1H))]
• CAS No.: 1132799-35-9
• Molecular Formula: C₄₈H₄₉CuFeN₂O₂P₂
• Molecular Weight: 867.27

Synonyms:[(1,1'-bis(diphenylphosphino)ferrocene)Cu(N,N'-di-n-butyl-2-amino-5-alcoholate-1,4-benzoquinonemonoiminium(-1H))]

Chemical Property of [(1,1'-bis(diphenylphosphino)ferrocene)Cu(N,N'-di-n-butyl-2-amino-5-alcoholate-1,4-benzoquinonemonoiminium(-1H))]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(1,1'-bis(diphenylphosphino)ferrocene)Cu(N,N'-di-n-butyl-2-amino-5-alcoholate-1,4-benzoquinonemonoiminium(-1H))]

There total 1 articles about [(1,1'-bis(diphenylphosphino)ferrocene)Cu(N,N'-di-n-butyl-2-amino-5-alcoholate-1,4-benzoquinonemonoiminium(-1H))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

[Cu2(μ-Cl)2(κ(2)-P,P-1,1'-bis(diphenylphosphino)ferrocene)2] + 4-(n-butylamino)-6-(n-butylimino)-3-oxocyclohexa-1,4-dien-1-olate (124251-43-0) → [(1,1'-bis(diphenylphosphino)ferrocene)Cu(N,N'-di-n-butyl-2-amino-5-alcoholate-1,4-benzoquinonemonoiminium(-1H))] (1132799-35-9)

Guidance literature:

With KOC(CH₃)3; In dichloromethane; byproducts: KCl; (Ar); ligand and THF added to KOC(CH3)3, stirred overnight at room temp., evapd. (vac.), Cu complex and CH2Cl2 added, stirred at room temp. for 4 h; filtered, concd. (vac.), n-hexane added, crystd. overnight at 4°C, filtered, washed (n-hexane); elem. anal.;

DOI:10.1021/ic802042w

Reference yield:

[(1,1'-bis(diphenylphosphino)ferrocene)Cu(N,N'-di-n-butyl-2-amino-5-alcoholate-1,4-benzoquinonemonoiminium(-1H))] (1132799-35-9) → [(1,1'-bis(diphenylphosphino)ferrocene)Cu(N,N'-di-n-butyl-2-amino-5-alcoholate-1,4-benzoquinonemonoiminium(-1H))](1+)

Guidance literature:

In further solvent(s); Electrochem. Process; (Ar); in CH2Cl2/N(C4H9)4PF6; not isolated, detected by ESR;

DOI:10.1021/ic802042w

Reference yield:

[Cu2(μ-Cl)2(κ(2)-P,P-1,1'-bis(diphenylphosphino)ferrocene)2] + dichloromethane (75-09-2) + [(1,1'-bis(diphenylphosphino)ferrocene)Cu(N,N'-di-n-butyl-2-amino-5-alcoholate-1,4-benzoquinonemonoiminium(-1H))] (1132799-35-9) → [(((diphenylphosphino)ferrocene)Cu)2(4-(n-butylamino)-6-(n-butylimino)-3-oxocyclohexa-1,4-dien-1-olate)]*2CH2Cl2

Guidance literature:

With NaH; Fe complex deprotonated with excess NaH; Cu complex added; 1H, 31H NMR;

DOI:10.1039/b921731b

upstream raw materials:

4-(n-butylamino)-6-(n-butylimino)-3-oxocyclohexa-1,4-dien-1-olate

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1132799-35-9 [(1,1'-bis(diphenylphosphino)ferrocene)Cu(N,N'-di-n-butyl-2-amino-5-alcoholate-1,4-benzoquinonemonoiminium(-1H))]

Send

Send

Metric Ton KG G Pound L ML

Send

Send