1-STYRYLNAPHTHALENE

Base Information

• Chemical Name: 1-STYRYLNAPHTHALENE
• CAS No.: 2043-00-7
• Molecular Formula: C₁₈H₁₄
• Molecular Weight: 230.309
• Hs Code.: 2902909090
• Mol file: 2043-00-7.mol

Synonyms:Naphthalene,1-styryl- (6CI,7CI,8CI); 1-(2-Phenylethenyl)naphthalene; 1-Styrylnaphthalene; a-Styrylnaphthalene

Chemical Property of 1-STYRYLNAPHTHALENE

Chemical Property:

• Vapor Pressure: 7.26E-06mmHg at 25°C
• Refractive Index: 1.718
• Boiling Point: 387.6°Cat760mmHg
• Flash Point: 180.7°C
• PSA: 0.00000
• Density: 1.113g/cm³
• LogP: 5.01020

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Styrylnaphthalene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-STYRYLNAPHTHALENE

There total 23 articles about 1-STYRYLNAPHTHALENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 1-Bromonaphthalene (90-11-9) → 1-styrylnaphthalene (2840-87-1,2840-88-2,85248-65-3,85248-66-4,2043-00-7)

Guidance literature:

With potassium phosphate; [((ferrocenyl)(C(CH₃)N(C₆H₄)CH₃))PdCl(N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)]; tetrabutylammomium bromide; In N,N-dimethyl-formamide; at 140 ℃; for 4h; Inert atmosphere;

DOI:10.1016/j.tet.2010.04.040

Reference yield: 97.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 1-phenylnaphthalene (605-02-7) → 1-styrylnaphthalene (2840-87-1,2840-88-2,85248-65-3,85248-66-4,2043-00-7)

Guidance literature:

With N-[2-(3,5-dimethylpyrazol-1-yl)phenyl]-N'-isopropylimidazol-2-ylidene palladium iodide acetate*AcOH*DCM; potassium carbonate; In water; N,N-dimethyl-formamide; Reagent/catalyst;

DOI:10.1007/s11243-013-9784-7

Reference yield: 93.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 1-Iodonaphthalene (90-14-2) → 1-styrylnaphthalene (2840-87-1,2840-88-2,85248-65-3,85248-66-4,2043-00-7)

Guidance literature:

With piperidine; In water; for 7h; Catalytic behavior; Reflux; Green chemistry;

DOI:10.1002/aoc.4856

upstream raw materials:

styrene

1-naphthyl triflate

1-naphthyldiazonium chloride

phenylmethylsulphonyl fluoride

Downstream raw materials:

chrysene

2-(1-naphthyl)-1-phenylethanedione

Refernces

• 1、 Nuri, Ayat,Bezaatpour, Abolfazl,Amiri, Mandana,Vucetic, Nemanja,Mikkola, Jyri-Pekka,Murzin, Dmitry Yu.. "Pd Nanoparticles Stabilized on the Cross-Linked Melamine-Based SBA-15 as a Catalyst for the Mizoroki–Heck Reaction". . p. 991 - 1002. Retrieved 2021/06/16.
• 2、 Liu, Qingxiang,Zhang, Xiantao,Zhao, Zhixiang,Li, Xinying,Zhang, Wei. "Synthesis of N-Heterocyclic Carbine Silver(I) and Palladium(II) Complexes with Acylated Piperazine Linker and Catalytic Activity in Three Types of C—C Coupling Reactions". supporting information. p. 605 - 613. Retrieved 2021/02/01.