nickel(II) 2-methyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin

Base Information

Chemical Name:nickel(II) 2-methyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin
CAS No.:163194-39-6
Molecular Formula:C₄₅H₃₀N₄Ni
Molecular Weight:685.45
Hs Code.:

Synonyms:nickel(II) 2-methyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of nickel(II) 2-methyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin

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Technology Process of nickel(II) 2-methyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin

There total 2 articles about nickel(II) 2-methyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 177841-46-2
(5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrinato)nickel(II)

: 74-88-4
methyl iodide

: 177841-51-9
(5,10,15,20-tetraphenyl-21-methyl-2-aza-21-carbaporphyrinato)nickel(II)

: 177841-48-4
NiI(N₄C₂₀H₇(CH₃)2(C₆H₅)4)

: 163194-39-6
nickel(II) 2-methyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin

Guidance literature:: With potassium carbonate; In ethanol; dichloromethane; under N2; mixt. of Ni complex and CH3I (7 equiv.) in CH2Cl2-EtOH contg. suspn. of K2CO3 refluxed for 3 h; solvent evapd. under reduced pressure; dissolved in CH2Cl2; chromd. (silica gel, CH2Cl2); second brown-reddish band collected (21-methylated Ni complex); crystd. from CH2Cl2-hexane; detd. by UV-vis and NMR spectra;
DOI:10.1021/ic034096k

Reference yield:

: 2-aza-2-methyl-5,10,15,20-tetraphenyl-21-carbaporphyrin

: 373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6
nickel diacetate

: 163194-39-6
nickel(II) 2-methyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin

Guidance literature:: In N,N-dimethyl-formamide; at 64.84 ℃; Temperature; Activation energy; Kinetics;
DOI:10.1039/c7nj01814b

Reference yield: 79.0%

: 163194-39-6
nickel(II) 2-methyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin

: 74-88-4
methyl iodide

: 177841-48-4
2-aza-2,21-dimethyl-5,10,15,20-tetraphenyl-21-carbaporphyrinatonickel(II) iodide

Guidance literature:: In dichloromethane; stirring (48 h); evapn. of the solvent, dissolution in CH2Cl2, pptn. with hexane; elem. anal.;
DOI:10.1021/ja9527028