2-aza-2,21-dimethyl-5,10,15,20-tetraphenyl-21-carbaporphyrinatonickel(II) iodide

Base Information

• Chemical Name: 2-aza-2,21-dimethyl-5,10,15,20-tetraphenyl-21-carbaporphyrinatonickel(II) iodide
• CAS No.: 177841-48-4
• Molecular Formula: C₄₆H₃₃IN₄Ni
• Molecular Weight: 827.389
• Mol file: 177841-48-4.mol

Synonyms:2-aza-2,21-dimethyl-5,10,15,20-tetraphenyl-21-carbaporphyrinatonickel(II) iodide

Chemical Property of 2-aza-2,21-dimethyl-5,10,15,20-tetraphenyl-21-carbaporphyrinatonickel(II) iodide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-aza-2,21-dimethyl-5,10,15,20-tetraphenyl-21-carbaporphyrinatonickel(II) iodide

There total 4 articles about 2-aza-2,21-dimethyl-5,10,15,20-tetraphenyl-21-carbaporphyrinatonickel(II) iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

nickel(II) 2-methyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin (163194-39-6) + methyl iodide (74-88-4) → 2-aza-2,21-dimethyl-5,10,15,20-tetraphenyl-21-carbaporphyrinatonickel(II) iodide (177841-48-4)

Guidance literature:

In dichloromethane; stirring (48 h); evapn. of the solvent, dissolution in CH2Cl2, pptn. with hexane; elem. anal.;

DOI:10.1021/ja9527028

Reference yield: 71.0%

(5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrinato)nickel(II) (177841-46-2) + methyl iodide (74-88-4) → (5,10,15,20-tetraphenyl-21-methyl-2-aza-21-carbaporphyrinato)nickel(II) (177841-51-9) + NiI(N4C20H7(CH3)2(C6H5)4) (177841-48-4) + nickel(II) 2-methyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin (163194-39-6)

Guidance literature:

With potassium carbonate; In ethanol; dichloromethane; under N2; mixt. of Ni complex and CH3I (7 equiv.) in CH2Cl2-EtOH contg. suspn. of K2CO3 refluxed for 3 h; solvent evapd. under reduced pressure; dissolved in CH2Cl2; chromd. (silica gel, CH2Cl2); second brown-reddish band collected (21-methylated Ni complex); crystd. from CH2Cl2-hexane; detd. by UV-vis and NMR spectra;

DOI:10.1021/ic034096k

Reference yield:

(5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrinato)nickel(II) (177841-46-2) + methyl iodide (74-88-4) → NiI(N4C20H7(CH3)2(C6H5)4) (177841-48-4)

Guidance literature:

With potassium carbonate; In ethanol; dichloromethane; under N2; mixt. of Ni complex and MeI (30-fold excess) in CH2Cl2-EtOH contg. suspn. of K2CO3 refluxed for 7 h;

DOI:10.1021/ic034096k

upstream raw materials:

nickel(II) 2-methyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin

methyl iodide

(5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrinato)nickel(II)

methyl bromide