(p-cymene)Ru(μ-Cl)₃RuCl(C₂H₄)(PCy₃)

Base Information

• Chemical Name: (p-cymene)Ru(μ-Cl)₃RuCl(C₂H₄)(PCy₃)
• CAS No.: 850167-17-8
• Molecular Formula: C₃₀H₅₁Cl₄PRu₂
• Molecular Weight: 786.661
• Mol file: 850167-17-8.mol

Synonyms:(p-cymene)Ru(μ-Cl)₃RuCl(C₂H₄)(PCy₃)

Chemical Property of (p-cymene)Ru(μ-Cl)₃RuCl(C₂H₄)(PCy₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (p-cymene)Ru(μ-Cl)₃RuCl(C₂H₄)(PCy₃)

There total 1 articles about (p-cymene)Ru(μ-Cl)₃RuCl(C₂H₄)(PCy₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + ethene (74-85-1) + tricyclohexylphosphine (2622-14-2) → (p-cymene)Ru(μ-Cl)3RuCl(C2H4)(PCy3) (850167-17-8)

Guidance literature:

In toluene; byproducts: CH3C6H4CH(CH3)2; (inert atm); heating mixt. of ruthenium compd. and phosphine deriv. in toluene under ethylene at 60°C;

DOI:10.1021/om900374e

Reference yield: 97.0%

(p-cymene)Ru(μ-Cl)3RuCl(C2H4)(PCy3) (850167-17-8) + 4-methoxyphenylacetylen (768-60-5) → [(p-cymene)Ru(μ-Cl)3RuCl(=C=CH-C6H4-4-OMe)(tricyclohexylphosphine)] (1258513-62-0)

Guidance literature:

In dichloromethane; byproducts: C2H4; (Ar); HC2C6H4OCH3 added to a soln. of Ru complex, stirred for 2 h at room temp.; evapd. (vac.), washed (n-pentane), dried overnight under vac.; elem. anal.;

DOI:10.1021/om1006177

Reference yield: 96.0%

di-tert-butylacetylene (17530-24-4) + (p-cymene)Ru(μ-Cl)3RuCl(C2H4)(PCy3) (850167-17-8) → (p-cymene)Ru(μ-Cl)3RuCl(PCy3)(CCH(tert-butyl))

Guidance literature:

In dichloromethane; under Ar, Schlenk techniques; metal compd. and ligand (128:154 molar ratio) stirred for 2 h; evapd. (vac.), washed (hexane), dried (vac.), recrystd. (toluene), elem.anal.;

DOI:10.1002/ejic.200600991

upstream raw materials:

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

ethene

tricyclohexylphosphine

Downstream raw materials:

[(cymene)Ru(μ-Cl)3RuCl(dihydrogen)(PCy3)]

[(p-cymene)Ru(μ-Cl)3RuCl(=C=CH-C6H4-3,5-(CF3)2)(tricyclohexylphosphine)]

[(p-cymene)Ru(μ-Cl)3RuCl(=C=CH-C6H4-4-OMe)(tricyclohexylphosphine)]

[(p-cymene)Ru(μ-Cl)3RuCl(=C=CH-C6H4-4-CF3)(tricyclohexylphosphine)]