benzyl 2-(((1S,4R)-4-acetoxycyclopent-2-en-1-yl)oxy)-2-(dimethoxyphosphoryl)acetate

Base Information

Chemical Name:benzyl 2-(((1S,4R)-4-acetoxycyclopent-2-en-1-yl)oxy)-2-(dimethoxyphosphoryl)acetate
CAS No.:1610375-31-9
Molecular Formula:C₁₈H₂₃O₈P
Molecular Weight:398.35
Hs Code.:

Synonyms:benzyl 2-(((1S,4R)-4-acetoxycyclopent-2-en-1-yl)oxy)-2-(dimethoxyphosphoryl)acetate

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Chemical Property of benzyl 2-(((1S,4R)-4-acetoxycyclopent-2-en-1-yl)oxy)-2-(dimethoxyphosphoryl)acetate

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Technology Process of benzyl 2-(((1S,4R)-4-acetoxycyclopent-2-en-1-yl)oxy)-2-(dimethoxyphosphoryl)acetate

There total 2 articles about benzyl 2-(((1S,4R)-4-acetoxycyclopent-2-en-1-yl)oxy)-2-(dimethoxyphosphoryl)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

: 60895-01-4,61348-01-4
3(S)-acetoxy-5-(R)-hydroxy-cyclopent-1-ene

: 1610375-30-8
benzyl (dimethylphosphono)diazoacetate

: 1610375-31-9
benzyl 2-(((1S,4R)-4-acetoxycyclopent-2-en-1-yl)oxy)-2-(dimethoxyphosphoryl)acetate

Guidance literature:: 3(S)-acetoxy-5-(R)-hydroxy-cyclopent-1-ene; benzyl (dimethylphosphono)diazoacetate; In benzene; for 0.0333333h; Inert atmosphere; Molecular sieve;

With dirhodium tetraacetate; In benzene; for 24h; Reflux; Inert atmosphere;

Reference yield:

: 57443-18-2
benzyl 2-(dimethoxyphosphoryl)acetate

: 1610375-31-9
benzyl 2-(((1S,4R)-4-acetoxycyclopent-2-en-1-yl)oxy)-2-(dimethoxyphosphoryl)acetate

Guidance literature:: Multi-step reaction with 2 steps

1.1: triethylamine; dodecylbenzenesulfonyl azide / acetonitrile / 20 - 40 °C

2.1: benzene / 0.03 h / Inert atmosphere; Molecular sieve

2.2: 24 h / Reflux; Inert atmosphere

With dodecylbenzenesulfonyl azide; triethylamine; In acetonitrile; benzene;

Reference yield: 21.0%

: 1610375-31-9
benzyl 2-(((1S,4R)-4-acetoxycyclopent-2-en-1-yl)oxy)-2-(dimethoxyphosphoryl)acetate

: 65-71-4,28806-14-6,691841-57-3
thymin

: 1610375-32-0
benzyl 2-(dimethoxyphosphoryl)-2-(((1S,4R)-4-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)cyclopent-2-en-1-yl)oxy)acetate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In acetonitrile; at 50 ℃; for 2h; Microwave irradiation; Inert atmosphere;