Methyl (2R,3S,4R,5S)-3,4,5-tris(benzyloxy)-6-<(tert-butyldimethylsilyl)oxy>-2-(methoxymethoxy)hexanoate

Base Information

Chemical Name:Methyl (2R,3S,4R,5S)-3,4,5-tris(benzyloxy)-6-<(tert-butyldimethylsilyl)oxy>-2-(methoxymethoxy)hexanoate
CAS No.:158535-92-3
Molecular Formula:C₃₆H₅₀O₈Si
Molecular Weight:638.874
Hs Code.:

Synonyms:Methyl (2R,3S,4R,5S)-3,4,5-tris(benzyloxy)-6-<(tert-butyldimethylsilyl)oxy>-2-(methoxymethoxy)hexanoate

Suppliers and Price of Methyl (2R,3S,4R,5S)-3,4,5-tris(benzyloxy)-6-<(tert-butyldimethylsilyl)oxy>-2-(methoxymethoxy)hexanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Methyl (2R,3S,4R,5S)-3,4,5-tris(benzyloxy)-6-<(tert-butyldimethylsilyl)oxy>-2-(methoxymethoxy)hexanoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Methyl (2R,3S,4R,5S)-3,4,5-tris(benzyloxy)-6-<(tert-butyldimethylsilyl)oxy>-2-(methoxymethoxy)hexanoate

There total 1 articles about Methyl (2R,3S,4R,5S)-3,4,5-tris(benzyloxy)-6-<(tert-butyldimethylsilyl)oxy>-2-(methoxymethoxy)hexanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (2S,3R,4R,5S,6E)-2,3,4-Tris(benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-5-(methoxymethoxy)-6-octene

: 158535-92-3
Methyl (2R,3S,4R,5S)-3,4,5-tris(benzyloxy)-6-<(tert-butyldimethylsilyl)oxy>-2-(methoxymethoxy)hexanoate

Guidance literature:: With sodium hydroxide; sodium tetrahydroborate; ozone; Yield given. Multistep reaction; 1.) CH₂Cl₂, MeOH, -78 deg C, 2.) MeOH, r.t., 5 min;
DOI:10.1021/jo00091a034

Reference yield: 98.0%

: 158535-92-3
Methyl (2R,3S,4R,5S)-3,4,5-tris(benzyloxy)-6-<(tert-butyldimethylsilyl)oxy>-2-(methoxymethoxy)hexanoate

: 158535-93-4
Methyl (2R,3S,4R,5S)-3,4,5-tris(benzyloxy)-6-hydroxy-2-(methoxymethoxy)hexanoate

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; acetic acid; for 20h; Ambient temperature;
DOI:10.1021/jo00091a034

Reference yield:

: 158535-92-3
Methyl (2R,3S,4R,5S)-3,4,5-tris(benzyloxy)-6-<(tert-butyldimethylsilyl)oxy>-2-(methoxymethoxy)hexanoate

: 158535-94-5
Methyl (2R,3S,4S,5R)-3,4,5-tris(benzyloxy)-2-(methoxymethoxy)-6-oxohexanoate

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / n-Bu₄NF / tetrahydrofuran; acetic acid / 20 h / Ambient temperature

2: 89 percent / Dess-Martin reagent / CH₂Cl₂ / 0.33 h / Ambient temperature

With tetrabutyl ammonium fluoride; Dess-Martin periodane; In tetrahydrofuran; dichloromethane; acetic acid;
DOI:10.1021/jo00091a034