[Mo(CO)2(η3-methallyl)(1,10-phenanthroline)(imidazole)][B(3,5-bis(trifluoro)phenyl)4]

Base Information

Chemical Name:[Mo(CO)2(η3-methallyl)(1,10-phenanthroline)(imidazole)][B(3,5-bis(trifluoro)phenyl)4]
CAS No.:1250442-41-1
Molecular Formula:C₂₁H₁₉MoN₄O₂*C₃₂H₁₂BF₂₄
Molecular Weight:1318.57
Hs Code.:

Synonyms:[Mo(CO)2(η3-methallyl)(1,10-phenanthroline)(imidazole)][B(3,5-bis(trifluoro)phenyl)4]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Mo(CO)2(η3-methallyl)(1,10-phenanthroline)(imidazole)][B(3,5-bis(trifluoro)phenyl)4]

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Technology Process of [Mo(CO)2(η3-methallyl)(1,10-phenanthroline)(imidazole)][B(3,5-bis(trifluoro)phenyl)4]

There total 1 articles about [Mo(CO)2(η3-methallyl)(1,10-phenanthroline)(imidazole)][B(3,5-bis(trifluoro)phenyl)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 288-32-4
1H-imidazole

: 12245-97-5,429657-89-6
(1,10-phenanthroline)(η3-2-methylallyl)dicarbonylmolybdenum chloride

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: 1250442-41-1
[Mo(CO)2(η3-methallyl)(1,10-phenanthroline)(imidazole)][B(3,5-bis(trifluoro)phenyl)4]

Guidance literature:: In dichloromethane; byproducts: NaCl; (N2, Schlenk technique); addn. of borate deriv. to CH2Cl2 soln. of molybdenum compd., stirring for 15 min at room temp., filtration, addn. of imidazole, keeping for 1 h; concg., addn. of hexane, isolation of ppt., washing with hexane, elem. anal.;
DOI:10.1021/ic1012395

Reference yield: 83.0%

: 1250442-41-1
[Mo(CO)2(η3-methallyl)(1,10-phenanthroline)(imidazole)][B(3,5-bis(trifluoro)phenyl)4]

: 639-58-7
triphenyltin chloride

: [(Mo(CO)2(η3-methallyl)(1,10-phenanthroline)(μ-imidazolate))2SnPh3][B(3,5-bis(trifluoro)phenyl)4]

Guidance literature:: With KN(Si(CH₃)3)2; In tetrahydrofuran; toluene; (N2, Schlenk technique); addn. of toluene soln. of potassium amide deriv. to THF soln. of molybdenum compd. at -78°C, stirring for 5 min at -78°C, addn. of THF soln. of tin compd., stirring for 15 min at room temp.; evapn., extn. (CH2Cl2), cannula filtration, concg., addn. of hexane, isolation of ppt., washing with hexane, recrystn. by slow diffusion of hexane to CH2Cl2 soln., elem. anal.;
DOI:10.1021/ic1012395