{[((2E,4Z)-4-bromo-4-{2-[3-(methoxymethyloxy)propyl]cyclohexylidene}-2-butenyl)oxy]methyl}benzene

Base Information

Chemical Name:{[((2E,4Z)-4-bromo-4-{2-[3-(methoxymethyloxy)propyl]cyclohexylidene}-2-butenyl)oxy]methyl}benzene
CAS No.:264134-86-3
Molecular Formula:C₂₂H₃₁BrO₃
Molecular Weight:423.39
Hs Code.:

Synonyms:{[((2E,4Z)-4-bromo-4-{2-[3-(methoxymethyloxy)propyl]cyclohexylidene}-2-butenyl)oxy]methyl}benzene

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Chemical Property of {[((2E,4Z)-4-bromo-4-{2-[3-(methoxymethyloxy)propyl]cyclohexylidene}-2-butenyl)oxy]methyl}benzene

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Technology Process of {[((2E,4Z)-4-bromo-4-{2-[3-(methoxymethyloxy)propyl]cyclohexylidene}-2-butenyl)oxy]methyl}benzene

There total 6 articles about {[((2E,4Z)-4-bromo-4-{2-[3-(methoxymethyloxy)propyl]cyclohexylidene}-2-butenyl)oxy]methyl}benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 100-44-7
benzyl chloride

: 273936-79-1
(2E,4Z)-4-bromo-4-{2-[3-(methoxymethyloxy)propyl]cyclohexylidene}-2-buten-1-ol

: 264134-86-3
{[((2E,4Z)-4-bromo-4-{2-[3-(methoxymethyloxy)propyl]cyclohexylidene}-2-butenyl)oxy]methyl}benzene

Guidance literature:: With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; In benzene; at 20 ℃; for 24h;
DOI:10.1021/ja9939284

Reference yield:

: 273936-78-0
ethyl (2E)-4-bromo-4-{2-[3-(methoxymethyloxy)propyl]cyclohexylidene}-2-butenoate

: 264134-86-3
{[((2E,4Z)-4-bromo-4-{2-[3-(methoxymethyloxy)propyl]cyclohexylidene}-2-butenyl)oxy]methyl}benzene

Guidance literature:: Multi-step reaction with 2 steps

1: 50 percent / DIBALH / CH₂Cl₂; hexane / 2 h / 0 °C

2: 89 percent / Bu₄N*HSO₄; aq. NaOH / benzene / 24 h / 20 °C

With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; diisobutylaluminium hydride; In hexane; dichloromethane; benzene; 1: Reduction / 2: Etherification;
DOI:10.1021/ja9939284

Reference yield:

: {2-[3-(methoxymethyloxy)propyl]cyclohexylidene}ethanal

: 264134-86-3
{[((2E,4Z)-4-bromo-4-{2-[3-(methoxymethyloxy)propyl]cyclohexylidene}-2-butenyl)oxy]methyl}benzene

Guidance literature:: Multi-step reaction with 4 steps

1.1: Br₂-dioxane

1.2: pyridine

2.1: NaH

3.1: 33 percent / DIBALH

4.1: NaOH

With sodium hydroxide; dioxane dibromide; sodium hydride; diisobutylaluminium hydride; 1.1: Bromination / 1.2: Dehydrobromination / 2.1: Horner-Emmons olefination / 3.1: Reduction / 4.1: Etherification;
DOI:10.1016/S0040-4039(99)02172-3