4-methyl-N-(2-methylallyl)-N-[(E)-3-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)-propenyl]-4-benzenesulfonamide

Base Information

Chemical Name:4-methyl-N-(2-methylallyl)-N-[(E)-3-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)-propenyl]-4-benzenesulfonamide
CAS No.:349458-91-9
Molecular Formula:C₂₀H₃₀BNO₄S
Molecular Weight:391.339
Hs Code.:

Synonyms:4-methyl-N-(2-methylallyl)-N-[(E)-3-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)-propenyl]-4-benzenesulfonamide

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Chemical Property of 4-methyl-N-(2-methylallyl)-N-[(E)-3-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)-propenyl]-4-benzenesulfonamide

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Technology Process of 4-methyl-N-(2-methylallyl)-N-[(E)-3-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)-propenyl]-4-benzenesulfonamide

There total 6 articles about 4-methyl-N-(2-methylallyl)-N-[(E)-3-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)-propenyl]-4-benzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 349458-89-5
4-methyl-N-(2-methylallyl)-N-[(E)-3-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)-vinyl]-4-benzenesulfonamide

: 593-71-5
Chloroiodomethane

: 349458-91-9
4-methyl-N-(2-methylallyl)-N-[(E)-3-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)-propenyl]-4-benzenesulfonamide

Guidance literature:: With n-butyllithium; In tetrahydrofuran; at -100 - 20 ℃; for 12h;
DOI:10.1039/b009259m

Reference yield:

: 4917-56-0
N-formyl-N-tosylamide

: 349458-91-9
4-methyl-N-(2-methylallyl)-N-[(E)-3-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)-propenyl]-4-benzenesulfonamide

Guidance literature:: Multi-step reaction with 5 steps

1: 37 percent / triethylamine / tetrahydrofuran / 24 h / 20 °C

2: 97 percent / triphenylphosphine / tetrahydrofuran / 55 °C

3: 95 percent / n-butyllithium / tetrahydrofuran; hexane / 2.5 h / -78 - -20 °C

4: 89 percent / zirconocene hydridochloride / CH₂Cl₂ / 8 h / 20 °C

5: 74 percent / n-butyllithium / tetrahydrofuran / 12 h / -100 - 20 °C

With Schwartz's reagent; n-butyllithium; triethylamine; triphenylphosphine; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1039/b009259m

Reference yield:

: 70-55-3
toluene-4-sulfonamide

: 349458-91-9
4-methyl-N-(2-methylallyl)-N-[(E)-3-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)-propenyl]-4-benzenesulfonamide

Guidance literature:: Multi-step reaction with 6 steps

1.1: sodium methoxide / methanol / 0.5 h / 40 °C

1.2: 83 percent / methanol / 6 h / 50 °C

2.1: 37 percent / triethylamine / tetrahydrofuran / 24 h / 20 °C

3.1: 97 percent / triphenylphosphine / tetrahydrofuran / 55 °C

4.1: 95 percent / n-butyllithium / tetrahydrofuran; hexane / 2.5 h / -78 - -20 °C

5.1: 89 percent / zirconocene hydridochloride / CH₂Cl₂ / 8 h / 20 °C

6.1: 74 percent / n-butyllithium / tetrahydrofuran / 12 h / -100 - 20 °C

With Schwartz's reagent; n-butyllithium; sodium methylate; triethylamine; triphenylphosphine; In tetrahydrofuran; methanol; hexane; dichloromethane;
DOI:10.1039/b009259m