{2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}dichlorophosphine

Base Information

• Chemical Name: {2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}dichlorophosphine
• CAS No.: 621110-83-6
• Molecular Formula: C₂₇H₅₉Cl₂PSi₆
• Molecular Weight: 654.158
• Mol file: 621110-83-6.mol

Synonyms:{2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}dichlorophosphine

Chemical Property of {2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}dichlorophosphine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}dichlorophosphine

There total 2 articles about {2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}dichlorophosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene (115160-05-9) → {2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}dichlorophosphine (621110-83-6)

Guidance literature:

1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 ℃; for 0.5h;

With phosphorus trichloride; In tetrahydrofuran; pentane; at -78 - 20 ℃; for 17h;

DOI:10.1002/poc.608

Reference yield:

{2,4,6-tris-(bis-(trimethylsilyl)methyl)phenyl}lithium (125444-10-2) → {2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}dichlorophosphine (621110-83-6)

Guidance literature:

With trichlorophosphate; In tetrahydrofuran;

DOI:10.1080/10426500490428906

Reference yield: 97.0%

{2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}dichlorophosphine (621110-83-6) → 2,4,6-tris[bis(trimethylsilyl)methyl]phenylphosphine

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1002/chem.200400577

upstream raw materials:

1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene

{2,4,6-tris-(bis-(trimethylsilyl)methyl)phenyl}lithium

Downstream raw materials:

bis(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)diphosphene

{2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}(dimethyl)phosphine