tert-butyl-[7-methoxymethoxy-12-(tetrahydropyran-2-yloxy)dodeca-(2Z,8E,10Z)-trienyloxy]diphenylsilane

Base Information

Chemical Name:tert-butyl-[7-methoxymethoxy-12-(tetrahydropyran-2-yloxy)dodeca-(2Z,8E,10Z)-trienyloxy]diphenylsilane
CAS No.:524956-53-4
Molecular Formula:C₃₅H₅₀O₅Si
Molecular Weight:578.865
Hs Code.:

Synonyms:tert-butyl-[7-methoxymethoxy-12-(tetrahydropyran-2-yloxy)dodeca-(2Z,8E,10Z)-trienyloxy]diphenylsilane

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Chemical Property of tert-butyl-[7-methoxymethoxy-12-(tetrahydropyran-2-yloxy)dodeca-(2Z,8E,10Z)-trienyloxy]diphenylsilane

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Technology Process of tert-butyl-[7-methoxymethoxy-12-(tetrahydropyran-2-yloxy)dodeca-(2Z,8E,10Z)-trienyloxy]diphenylsilane

There total 5 articles about tert-butyl-[7-methoxymethoxy-12-(tetrahydropyran-2-yloxy)dodeca-(2Z,8E,10Z)-trienyloxy]diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 107-30-2
chloromethyl methyl ether

: 524956-52-3
12-(tert-butyldiphenylsilanyloxy)-1-(tetrahydropyran-2-yloxy)dodeca-(2Z,4E,10Z)-trien-6-ol

: 524956-53-4
tert-butyl-[7-methoxymethoxy-12-(tetrahydropyran-2-yloxy)dodeca-(2Z,8E,10Z)-trienyloxy]diphenylsilane

Guidance literature:: With potassium hexamethylsilazane; In tetrahydrofuran; at 0 - 70 ℃; for 2h;
DOI:10.1139/v02-064

Reference yield:

: 119119-20-9
(2E,4Z)-6-(Tetrahydro-pyran-2-yloxy)-hexa-2,4-dienal

: 524956-53-4
tert-butyl-[7-methoxymethoxy-12-(tetrahydropyran-2-yloxy)dodeca-(2Z,8E,10Z)-trienyloxy]diphenylsilane

Guidance literature:: Multi-step reaction with 2 steps

1.1: tert-butyllithium / diethyl ether / 0.17 h / -78 °C

1.2: 92 percent / diethyl ether / 0.42 h / -78 - 20 °C

2.1: 97 percent / potassium bis(trimethylsilyl)amide / tetrahydrofuran / 2 h / 0 - 70 °C

With tert.-butyl lithium; potassium hexamethylsilazane; In tetrahydrofuran; diethyl ether;
DOI:10.1139/v02-064

Reference yield:

: 307497-58-1
(4Z)-6-(tert-butyldiphenylsilyloxy)-4-hexen-1-ol

: 524956-53-4
tert-butyl-[7-methoxymethoxy-12-(tetrahydropyran-2-yloxy)dodeca-(2Z,8E,10Z)-trienyloxy]diphenylsilane

Guidance literature:: Multi-step reaction with 4 steps

1.1: triethylamine / CH₂Cl₂ / 1 h / 0 °C

2.1: 15.14 g / sodium iodide / acetone / 1.5 h / Heating

3.1: tert-butyllithium / diethyl ether / 0.17 h / -78 °C

3.2: 92 percent / diethyl ether / 0.42 h / -78 - 20 °C

4.1: 97 percent / potassium bis(trimethylsilyl)amide / tetrahydrofuran / 2 h / 0 - 70 °C

With tert.-butyl lithium; potassium hexamethylsilazane; triethylamine; sodium iodide; In tetrahydrofuran; diethyl ether; dichloromethane; acetone;
DOI:10.1139/v02-064