ethyl 3-hydroxy-3-{4-[(4-{[(2Z)-2-(methoxyimino)-2-phenylethyl]oxy}benzyl)oxy]phenyl}propanoate

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Chemical Name:ethyl 3-hydroxy-3-{4-[(4-{[(2Z)-2-(methoxyimino)-2-phenylethyl]oxy}benzyl)oxy]phenyl}propanoate
CAS No.:1356602-59-9
Molecular Formula:C₂₇H₂₉NO₆
Molecular Weight:463.53
Hs Code.:

Synonyms:ethyl 3-hydroxy-3-{4-[(4-{[(2Z)-2-(methoxyimino)-2-phenylethyl]oxy}benzyl)oxy]phenyl}propanoate

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Chemical Property of ethyl 3-hydroxy-3-{4-[(4-{[(2Z)-2-(methoxyimino)-2-phenylethyl]oxy}benzyl)oxy]phenyl}propanoate

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Technology Process of ethyl 3-hydroxy-3-{4-[(4-{[(2Z)-2-(methoxyimino)-2-phenylethyl]oxy}benzyl)oxy]phenyl}propanoate

There total 8 articles about ethyl 3-hydroxy-3-{4-[(4-{[(2Z)-2-(methoxyimino)-2-phenylethyl]oxy}benzyl)oxy]phenyl}propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.5%

: 1356602-57-7
ethyl 3-hydroxy-3-{4-[(4-{[(2Z)-2-(methoxyimino)-2-phenylethyl]oxy}benzyl)oxy]phenyl}-2-(phenylsulfanyl)propanoate

: 1356602-59-9
ethyl 3-hydroxy-3-{4-[(4-{[(2Z)-2-(methoxyimino)-2-phenylethyl]oxy}benzyl)oxy]phenyl}propanoate

Guidance literature:: With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile); In benzene; at 80 ℃; for 4h;

Reference yield:

: 70-11-1
α-bromoacetophenone

: 1356602-59-9
ethyl 3-hydroxy-3-{4-[(4-{[(2Z)-2-(methoxyimino)-2-phenylethyl]oxy}benzyl)oxy]phenyl}propanoate

Guidance literature:: Multi-step reaction with 8 steps

1.1: sodium acetate; acetic acid / 0.08 h / 20 °C

1.2: 3 h / 20 - 80 °C

2.1: potassium carbonate / acetonitrile / 0.08 h / 20 °C

2.2: 5 h / 20 - 80 °C

3.1: triphenylphosphine; di-isopropyl azodicarboxylate / tetrahydrofuran / 12 h / 0 - 20 °C

4.1: sodium hydride / tetrahydrofuran / 0.5 h / 0 °C

4.2: 12 h / 0 - 20 °C

5.1: osmium(VIII) oxide; potassium hexacyanoferrate(III); methanesulfonamide; hydroquinidein 1,4-phthalazinediyl diether / water; tert-butyl alcohol / 12 h / 0 - 20 °C

6.1: pyridine / dichloromethane / 4 h / -78 - 20 °C

7.1: triethylamine / tetrahydrofuran / 12 h / 20 - 60 °C / Inert atmosphere

8.1: tri-n-butyl-tin hydride / 2,2'-azobis(isobutyronitrile) / benzene / 4 h / 80 °C

With pyridine; osmium(VIII) oxide; methanesulfonamide; di-isopropyl azodicarboxylate; tri-n-butyl-tin hydride; sodium acetate; sodium hydride; potassium carbonate; acetic acid; hydroquinidein 1,4-phthalazinediyl diether; triethylamine; triphenylphosphine; potassium hexacyanoferrate(III); 2,2'-azobis(isobutyronitrile); In tetrahydrofuran; dichloromethane; water; acetonitrile; tert-butyl alcohol; benzene;

Reference yield:

: 142533-52-6
(Z)-2-bromo-1-phenylethanone O-methyl oxime

: 1356602-59-9
ethyl 3-hydroxy-3-{4-[(4-{[(2Z)-2-(methoxyimino)-2-phenylethyl]oxy}benzyl)oxy]phenyl}propanoate

Guidance literature:: Multi-step reaction with 7 steps

1.1: potassium carbonate / acetonitrile / 0.08 h / 20 °C

1.2: 5 h / 20 - 80 °C

2.1: triphenylphosphine; di-isopropyl azodicarboxylate / tetrahydrofuran / 12 h / 0 - 20 °C

3.1: sodium hydride / tetrahydrofuran / 0.5 h / 0 °C

3.2: 12 h / 0 - 20 °C

4.1: osmium(VIII) oxide; potassium hexacyanoferrate(III); methanesulfonamide; hydroquinidein 1,4-phthalazinediyl diether / water; tert-butyl alcohol / 12 h / 0 - 20 °C

5.1: pyridine / dichloromethane / 4 h / -78 - 20 °C

6.1: triethylamine / tetrahydrofuran / 12 h / 20 - 60 °C / Inert atmosphere

7.1: tri-n-butyl-tin hydride / 2,2'-azobis(isobutyronitrile) / benzene / 4 h / 80 °C

With pyridine; osmium(VIII) oxide; methanesulfonamide; di-isopropyl azodicarboxylate; tri-n-butyl-tin hydride; sodium hydride; potassium carbonate; hydroquinidein 1,4-phthalazinediyl diether; triethylamine; triphenylphosphine; potassium hexacyanoferrate(III); 2,2'-azobis(isobutyronitrile); In tetrahydrofuran; dichloromethane; water; acetonitrile; tert-butyl alcohol; benzene;