Pt(((C₆H₅)2PC₅H₄)2Fe)(CHCHC₆H₄OCH₃)⁽¹⁺⁾*Br^(1-)=[Pt(((C₆H₅)2PC₅H₄)2Fe)(CHCHC₆H₄OCH₃)]Br

Base Information

• Chemical Name: Pt(((C₆H₅)2PC₅H₄)2Fe)(CHCHC₆H₄OCH₃)⁽¹⁺⁾*Br^(1-)=[Pt(((C₆H₅)2PC₅H₄)2Fe)(CHCHC₆H₄OCH₃)]Br
• CAS No.: 123886-28-2
• Molecular Formula: C₄₃H₃₇BrFeOP₂Pt
• Molecular Weight: 962.545
• Mol file: 123886-28-2.mol

Synonyms:Pt(((C₆H₅)2PC₅H₄)2Fe)(CHCHC₆H₄OCH₃)⁽¹⁺⁾*Br^(1-)=[Pt(((C₆H₅)2PC₅H₄)2Fe)(CHCHC₆H₄OCH₃)]Br

Chemical Property of Pt(((C₆H₅)2PC₅H₄)2Fe)(CHCHC₆H₄OCH₃)⁽¹⁺⁾*Br^(1-)=[Pt(((C₆H₅)2PC₅H₄)2Fe)(CHCHC₆H₄OCH₃)]Br

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pt(((C₆H₅)2PC₅H₄)2Fe)(CHCHC₆H₄OCH₃)⁽¹⁺⁾*Br^(1-)=[Pt(((C₆H₅)2PC₅H₄)2Fe)(CHCHC₆H₄OCH₃)]Br

There total 3 articles about Pt(((C₆H₅)2PC₅H₄)2Fe)(CHCHC₆H₄OCH₃)⁽¹⁺⁾*Br^(1-)=[Pt(((C₆H₅)2PC₅H₄)2Fe)(CHCHC₆H₄OCH₃)]Br which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

norborn-2-ene (498-66-8) + sodium tetrahydroborate (16940-66-2) + [1,1'-bis(diphenylphosphino)ferrocene]platinum(II) chloride (104413-90-3) + (E)-4-(2-bromo-vinyl)-anisole (6303-59-9,60592-52-1,27570-08-7) → {1,1'-bis(diphenylphosphino)ferrocene}bromo{(E)-2-(4-methoxyphenyl)vinyl}platinum (123886-28-2)

Guidance literature:

In ethanol; dichloromethane; Ar-atmosphere; NaBH4 addn. to mixt. of Pt-complex and norbornene (stirring), filtration, dissoln. in CH2Cl2, addn. of substituted alkene; crystn. on Et2O addn. (-20°C); elem. anal.;

DOI:10.1021/om00116a010

Reference yield:

[1,1'-bis(diphenylphosphino)ferrocene]platinum(II) chloride (104413-90-3) + 4-(2-bromo-vinyl)-anisole (27570-08-7,60592-52-1,6303-59-9) → Pt(((C6H5)2PC5H4)2Fe)(CHCHC6H4OCH3)(1+)*Br(1-)=[Pt(((C6H5)2PC5H4)2Fe)(CHCHC6H4OCH3)]Br (123886-28-2) + [Pt2((Ph2PC5H4)2Fe)2(μ-CHCH2-p-MeOC6H4)(μ-H)]Br

Guidance literature:

With norbornene; NaBH₄; In ethanol; dichloromethane; N2-atmosphere; stirring (3 h), alkene addn., stirring (2 d); filtering, evapn., crystn. (CH2Cl2, -20°C); elem. anal.;

DOI:10.1021/om9708034

Reference yield:

{1,1'-bis(diphenylphosphino)ferrocene}{η2-(E)-2-bromo-1-(4-methoxyphenyl)ethene}platinum (123860-24-2) → {1,1'-bis(diphenylphosphino)ferrocene}bromo{(E)-2-(4-methoxyphenyl)vinyl}platinum (123886-28-2)

Guidance literature:

In tetrahydrofuran; diethyl ether; Ar-atmosphere; ambient temp., 1 week in dark; not isolated, determined by NMR spectroscopy;

DOI:10.1021/om00116a010

upstream raw materials:

norborn-2-ene

sodium tetrahydroborate

[1,1'-bis(diphenylphosphino)ferrocene]platinum(II) chloride

(E)-4-(2-bromo-vinyl)-anisole

Downstream raw materials:

Pt{1,1'-bis(diphenylphosphino)ferrocene}(η2-CH3OC6H4CH=CHC6H4OCH3)

Pt{1,1'-bis(diphenylphosphino)ferrocene}(C₆H₄OCH₃)(CH=CHC₆H₄OCH₃)