cis,cis-6,13,17-triphenyl-6,13,17-triphospha-2thiatricyclo<16.4.0.0^7,12>docosa-7(12),8,10,1(18),19,21-hexaene

Base Information

• Chemical Name: cis,cis-6,13,17-triphenyl-6,13,17-triphospha-2thiatricyclo<16.4.0.0^7,12>docosa-7(12),8,10,1(18),19,21-hexaene
• CAS No.: 94890-91-2
• Molecular Formula: C₃₆H₃₅P₃S
• Molecular Weight: 592.661

Synonyms:cis,cis-6,13,17-triphenyl-6,13,17-triphospha-2thiatricyclo<16.4.0.0^7,12>docosa-7(12),8,10,1(18),19,21-hexaene

Chemical Property of cis,cis-6,13,17-triphenyl-6,13,17-triphospha-2thiatricyclo<16.4.0.0^7,12>docosa-7(12),8,10,1(18),19,21-hexaene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of cis,cis-6,13,17-triphenyl-6,13,17-triphospha-2thiatricyclo<16.4.0.0^7,12>docosa-7(12),8,10,1(18),19,21-hexaene

There total 7 articles about cis,cis-6,13,17-triphenyl-6,13,17-triphospha-2thiatricyclo<16.4.0.0^7,12>docosa-7(12),8,10,1(18),19,21-hexaene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

1,2-diphenylphosphinobenzene (38023-29-9) + 2-((3'-chloropropyl)phenylphosphino)-1-((3-chloropropyl)thio)benzene (94890-94-5) → cis,trans-6,13,17-triphenyl-6,13,17-triphospha-2thiatricyclo<16.4.0.07,12>docosa-7(12),8,10,1(18),19,21-hexaene (94942-82-2) + cis,cis-6,13,17-triphenyl-6,13,17-triphospha-2thiatricyclo<16.4.0.07,12>docosa-7(12),8,10,1(18),19,21-hexaene (94890-91-2)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃;

DOI:10.1021/ja00293a052

Reference yield:

diethyl phenylphosphonite (1638-86-4) → cis,cis-6,13,17-triphenyl-6,13,17-triphospha-2thiatricyclo<16.4.0.07,12>docosa-7(12),8,10,1(18),19,21-hexaene (94890-91-2)

Guidance literature:

Multi-step reaction with 5 steps

1: 25 °C

2: Fe, NH₄Cl / H₂O / Heating

4: 1.80 M n-butyllithium / hexane; tetrahydrofuran / -78 °C

5: 5 percent / 1.80 M n-butyllithium / hexane; tetrahydrofuran / -78 °C

With n-butyllithium; iron; ammonium chloride; In tetrahydrofuran; hexane; water;

DOI:10.1021/ja00293a052

Reference yield:

Ethyl-(o-nitrophenyl)-phenylphosphinat (65000-89-7) → cis,cis-6,13,17-triphenyl-6,13,17-triphospha-2thiatricyclo<16.4.0.07,12>docosa-7(12),8,10,1(18),19,21-hexaene (94890-91-2)

Guidance literature:

Multi-step reaction with 4 steps

1: Fe, NH₄Cl / H₂O / Heating

3: 1.80 M n-butyllithium / hexane; tetrahydrofuran / -78 °C

4: 5 percent / 1.80 M n-butyllithium / hexane; tetrahydrofuran / -78 °C

With n-butyllithium; iron; ammonium chloride; In tetrahydrofuran; hexane; water;

DOI:10.1021/ja00293a052

upstream raw materials:

1,2-diphenylphosphinobenzene

2-((3'-chloropropyl)phenylphosphino)-1-((3-chloropropyl)thio)benzene

cis,trans-6,13,17-triphenyl-6,13,17-triphospha-2thiatricyclo<16.4.0.0^7,12>docosa-7(12),8,10,1(18),19,21-hexaene

diethyl phenylphosphonite

Downstream raw materials:

cis,trans-6,13,17-triphenyl-6,13,17-triphospha-2thiatricyclo<16.4.0.0^7,12>docosa-7(12),8,10,1(18),19,21-hexaene

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